Theoretical Insights into the Role of a Counterion in Copper-Catalyzed Enantioselective Cyclopropanation Reactions

Chemistry - A European Journal

Volumn 10, Issue 3, 2004, Pages 758-765

  Fraile, José M ^a   García, José I ^a   Gil, María J ^b   Martínez Merino, Víctor ^b   Mayoral, José A ^a   Salvatella, Luis ^a  

^a UNIVERSITY OF ZARAGOZA   (Spain)

^b PUBLIC UNIVERSITY OF NAVARRE   (Spain)

Author keywords

Asymmetric catalysis; Copper; Cyclopropanation; Density functional calculations; Ligand effects; N ligands

Indexed keywords

CATALYSTS; DIMERS; ESTERS; POSITIVE IONS;

CYCLOPROPANATION; TRANSITION STRUCTURES;

COPPER;

BIS(OXAZOLINE)COPPER; CARBENE; CHLORIDE ION; COPPER DERIVATIVE; CYCLOPROPANE; DIMER; ESTER DERIVATIVE; ION; METAL; NITROGEN; UNCLASSIFIED DRUG;

ARTICLE; CALCULATION; CATALYSIS; CATALYST; CHEMICAL STRUCTURE; CHIRALITY; CYCLOPROPANATION; ENANTIOSELECTIVITY; GEOMETRY; MODEL; REACTION ANALYSIS; STEREOCHEMISTRY; STRUCTURE ANALYSIS;

EID: 1242307865     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200305161     Document Type: Article

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