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note
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Mounds reaching sizes larger than 3 um were not observed due to contact with neighboring mounds. At this size most mounds begin to connect to nearest neighbors, forming irregular bunches of what was initially several different mounds.
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9
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1242320002
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note
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The Hamaker constant for both Ag and Au nanocrystals is -20% higher in hexane than chloroform. However, the Hamaker constant for Ag nanocrystals is 18% lower in magnitude than that of Au in both solvents.
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14
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1242320000
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note
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Bond energies for individual nanocrystals attaching to a kink, step, and terrace site of the colloidal crystal were determined from the pontential wells located in the Supporting Information. For gold nanocrystals in hexane, incorporation into a kink site is 2.178/kT or 0.056 eV, versus 1.815/kT or 0.047 eV for a step and 1.089/kT or 0.028 eV for a terrace. For gold in chloroform, bonding in 0.048 eV for a kink, 0.040 eV for a step, and 0.024 eV for a terrace site.
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19
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0347870623
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