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As mentioned above, the LJ parameters determined for the polydisperse samples listed in Table I represent “average” values for those samples. Therefore, the fact that real samples have a narrow (yet finite) size distribution is somewhat reflected in the calculated values of (Formula presented) Since the size distributions of the polydisperse and monodisperse samples differ by only ∼5%, the parameter values were not corrected to account for these minimal differences.
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As mentioned above, the LJ parameters determined for the polydisperse samples listed in Table I represent “average” values for those samples. Therefore, the fact that real samples have a narrow (yet finite) size distribution is somewhat reflected in the calculated values of (Formula presented) Since the size distributions of the polydisperse and monodisperse samples differ by only ∼5%, the parameter values were not corrected to account for these minimal differences.
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