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85187114981
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note
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To a solution of alkyl azide (1 equiv) and methyl acetoacetate (2 equiv) in EtOAc was added a catalytic amount of 10% Pd/C (∼10% weight) and the reaction mixture was stirred under hydrogen (balloon) at room temperature. After 0.5-2 h, the catalyst was filtered off and the residue obtained after the removal of all volatiles, passed through a small silica gel plug to furnish the desired products as a Z:E mixture
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85187105231
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See supporting information for characterization of all new compounds characterization
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46
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37049113285
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85187113828
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note
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This reaction was not optimised
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