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The viscosity of the solution changes by the addition of quencher. For instance, the viscosity of liquid paraffin containing 0.15 M TMPD is 87.5 cP at 296 K. The value 104 cP of the pure solvent was nevertheless used as η to calculate D by eq 4, since the volume fraction of the added TMPD is small (of the order of 1%) compared to that of the solvent and the molecules are considered to diffuse in an environment which is approximately the same as that of the pure solvent. The change in the η value affects the A and b values obtained by the procedure described later, but does not affect the qualitative conclusion of this paper.
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