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Volumn 103, Issue 30, 1999, Pages 5882-5888

Transient Effect in Fluorescence Quenching by Electron Transfer. 4. Long-Range Electron Transfer in a Nonpolar Solvent

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EID: 0000003964     PISSN: 10895639     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp991087h     Document Type: Article
Times cited : (56)

References (30)
  • 16
    • 85034131322 scopus 로고    scopus 로고
    • note
    • The viscosity of the solution changes by the addition of quencher. For instance, the viscosity of liquid paraffin containing 0.15 M TMPD is 87.5 cP at 296 K. The value 104 cP of the pure solvent was nevertheless used as η to calculate D by eq 4, since the volume fraction of the added TMPD is small (of the order of 1%) compared to that of the solvent and the molecules are considered to diffuse in an environment which is approximately the same as that of the pure solvent. The change in the η value affects the A and b values obtained by the procedure described later, but does not affect the qualitative conclusion of this paper.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.