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The diameters of a large number of spheres (typically - 200 spheres) were obtained from scanned TEM images processed using ImageJ and tabulated. The size distribution, defined as the standard deviation divided by the mean sphere diameter, was subsequently evaluated as such for all samples reported.
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Although the quantum yields of as-synthesized core-shell CdSe/ZnS NCs used were as high as 38%. subsequent loss of the original surface ligands due to cap-exchange with AP and APS can lead to diminished quantum yields. Furthermore, the decline in the quantum yield due to processing is very dependent on the quality and thickness of the ZnS shell on the NCs, which can vary from sample to sample.
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The standard deviation is more significant than the absolute value of the ratio due to the curvature of the microsphere, which may introduce inherent systematic error into the WDS measurement.
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