Photophysical properties changes caused by hypercoordination of organosilicon compounds: From trianthrylfluorosilane to trianthryldifluorosilicate [15]

Journal of the American Chemical Society

Volumn 122, Issue 28, 2000, Pages 6793-6794

  Yamaguchi, Shigehiro ^a   Akiyama, Seiji ^a   Tamao, Kohei ^a  

^a KYOTO UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ORGANOSILICON DERIVATIVE; SILANE DERIVATIVE;

CHEMICAL STRUCTURE; ELECTRON TRANSPORT; JAPAN; LETTER; MOLECULAR INTERACTION; PHOTOCHEMISTRY;

EID: 0034686727     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja001042q     Document Type: Letter

References (33)

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7. For examples: (a) Salzner, U.; Lagowski, J. B.; Pickup, P. G.; Poirier, R. A. Synth. Met. 1998, 96, 177. (b) Eisch, J. J.; Galle, J. E.; Kozima, S. J. Am. Chem. Soc. 1986, 108, 379. (c) Yuan, Z.; Taylor, N. J.; Ramachandran, R.; Marder, T. B. Appl. Organomet. Chem. 1996, 10, 305. (d) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 5112. (e) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 10776. (f) Noda, T.; Shirota, Y. J. Am. Chem. Soc. 1998, 120, 9714. (g) Yamaguchi, S.; Tamao, K. J. Chem. Soc., Dalton Trans., 1998, 3693. (h) Yamaguchi, S.; Itamai, Y.; Tamao, K. Organometallics 1998, 17, 4910. (i) Deschamps, E.; Ricard, L.; Mathey, F. Angew. Chem., Int. Ed. Engl. 1994, 33, 1158. (j) Hay, C.; Vilain, D. L.; Deborde, V.; Toupet, L.; Réau, T. Chem. Commun. 1999, 345. (k) Mao, S. S.; Tilley, T. D. Macromolecules 1997, 30, 5566. (l) Barbarella, G.; Favaretto, L.; Sotgiu, G.; Zambianchi, M.; Antolini, L.; Pudova, O.; Bongini, A. J. Org. Chem. 1998, 63, 5497. (m) Jiang, B.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9744.
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9. For examples: (a) Salzner, U.; Lagowski, J. B.; Pickup, P. G.; Poirier, R. A. Synth. Met. 1998, 96, 177. (b) Eisch, J. J.; Galle, J. E.; Kozima, S. J. Am. Chem. Soc. 1986, 108, 379. (c) Yuan, Z.; Taylor, N. J.; Ramachandran, R.; Marder, T. B. Appl. Organomet. Chem. 1996, 10, 305. (d) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 5112. (e) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 10776. (f) Noda, T.; Shirota, Y. J. Am. Chem. Soc. 1998, 120, 9714. (g) Yamaguchi, S.; Tamao, K. J. Chem. Soc., Dalton Trans., 1998, 3693. (h) Yamaguchi, S.; Itamai, Y.; Tamao, K. Organometallics 1998, 17, 4910. (i) Deschamps, E.; Ricard, L.; Mathey, F. Angew. Chem., Int. Ed. Engl. 1994, 33, 1158. (j) Hay, C.; Vilain, D. L.; Deborde, V.; Toupet, L.; Réau, T. Chem. Commun. 1999, 345. (k) Mao, S. S.; Tilley, T. D. Macromolecules 1997, 30, 5566. (l) Barbarella, G.; Favaretto, L.; Sotgiu, G.; Zambianchi, M.; Antolini, L.; Pudova, O.; Bongini, A. J. Org. Chem. 1998, 63, 5497. (m) Jiang, B.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9744.
10. For examples: (a) Salzner, U.; Lagowski, J. B.; Pickup, P. G.; Poirier, R. A. Synth. Met. 1998, 96, 177. (b) Eisch, J. J.; Galle, J. E.; Kozima, S. J. Am. Chem. Soc. 1986, 108, 379. (c) Yuan, Z.; Taylor, N. J.; Ramachandran, R.; Marder, T. B. Appl. Organomet. Chem. 1996, 10, 305. (d) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 5112. (e) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 10776. (f) Noda, T.; Shirota, Y. J. Am. Chem. Soc. 1998, 120, 9714. (g) Yamaguchi, S.; Tamao, K. J. Chem. Soc., Dalton Trans., 1998, 3693. (h) Yamaguchi, S.; Itamai, Y.; Tamao, K. Organometallics 1998, 17, 4910. (i) Deschamps, E.; Ricard, L.; Mathey, F. Angew. Chem., Int. Ed. Engl. 1994, 33, 1158. (j) Hay, C.; Vilain, D. L.; Deborde, V.; Toupet, L.; Réau, T. Chem. Commun. 1999, 345. (k) Mao, S. S.; Tilley, T. D. Macromolecules 1997, 30, 5566. (l) Barbarella, G.; Favaretto, L.; Sotgiu, G.; Zambianchi, M.; Antolini, L.; Pudova, O.; Bongini, A. J. Org. Chem. 1998, 63, 5497. (m) Jiang, B.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9744.
11. For examples: (a) Salzner, U.; Lagowski, J. B.; Pickup, P. G.; Poirier, R. A. Synth. Met. 1998, 96, 177. (b) Eisch, J. J.; Galle, J. E.; Kozima, S. J. Am. Chem. Soc. 1986, 108, 379. (c) Yuan, Z.; Taylor, N. J.; Ramachandran, R.; Marder, T. B. Appl. Organomet. Chem. 1996, 10, 305. (d) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 5112. (e) Matsumi, N.; Naka, K.; Chujo, Y. J. Am. Chem. Soc. 1998, 120, 10776. (f) Noda, T.; Shirota, Y. J. Am. Chem. Soc. 1998, 120, 9714. (g) Yamaguchi, S.; Tamao, K. J. Chem. Soc., Dalton Trans., 1998, 3693. (h) Yamaguchi, S.; Itamai, Y.; Tamao, K. Organometallics 1998, 17, 4910. (i) Deschamps, E.; Ricard, L.; Mathey, F. Angew. Chem., Int. Ed. Engl. 1994, 33, 1158. (j) Hay, C.; Vilain, D. L.; Deborde, V.; Toupet, L.; Réau, T. Chem. Commun. 1999, 345. (k) Mao, S. S.; Tilley, T. D. Macromolecules 1997, 30, 5566. (l) Barbarella, G.; Favaretto, L.; Sotgiu, G.; Zambianchi, M.; Antolini, L.; Pudova, O.; Bongini, A. J. Org. Chem. 1998, 63, 5497. (m) Jiang, B.; Tilley, T. D. J. Am. Chem. Soc. 1999, 121, 9744.
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15. Hypercoordinate silicon compounds, reviews: (a) Tandura, S. N.; Alekseev, N. V.; Voronkov, M. G. Top. Curr. Chem. 1986, 131, 99. (b) Corriu, R. J. P.; Young, J. C. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley: Chichester, 1989; p 1241. (c) Chuit, C.; Corriu, R. J. P.; Reyé, C.; Young, J. C. Chem. Rev. 1993, 93, 1371. (d) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z.; Apeloig, Y., Eds.; John Wiley: Chichester, 1998; Vol. 2, Part 2, p 1339.
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17. Hypercoordinate silicon compounds, reviews: (a) Tandura, S. N.; Alekseev, N. V.; Voronkov, M. G. Top. Curr. Chem. 1986, 131, 99. (b) Corriu, R. J. P.; Young, J. C. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley: Chichester, 1989; p 1241. (c) Chuit, C.; Corriu, R. J. P.; Reyé, C.; Young, J. C. Chem. Rev. 1993, 93, 1371. (d) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z.; Apeloig, Y., Eds.; John Wiley: Chichester, 1998; Vol. 2, Part 2, p 1339.
18. Hypercoordinate silicon compounds, reviews: (a) Tandura, S. N.; Alekseev, N. V.; Voronkov, M. G. Top. Curr. Chem. 1986, 131, 99. (b) Corriu, R. J. P.; Young, J. C. In The Chemistry of Organic Silicon Compounds; Patai, S., Rappoport, Z., Eds.; John Wiley: Chichester, 1989; p 1241. (c) Chuit, C.; Corriu, R. J. P.; Reyé, C.; Young, J. C. Chem. Rev. 1993, 93, 1371. (d) Kost, D.; Kalikhman, I. In The Chemistry of Organic Silicon Compounds; Rappoport, Z.; Apeloig, Y., Eds.; John Wiley: Chichester, 1998; Vol. 2, Part 2, p 1339.
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21. 6Si: C, 71.12; H, 6.27; N, 2.76. Found: C, 71.41; H, 6.14; N, 2.93.
22. w = 0.053, and GOF = 1.18.
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24. +/[2.2.2]cryptand: See the Supporting Information.
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