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For some recent methods for the synthesis of optically active cyclopentanoids see: Ho T.-L. Carbocyclic Construction in Terpene Synthesis. 1988;VCH, Weinheim.
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Ho, T.-L.1
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Kerr W.J., Lindsay D.M., Rankin E.M., Scott J.S., Watson S.P. Tetrahedron Lett. 41:2000;3229.
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Son S.U., Park K.H., Seo H., Chung Y.K., Lee S.-G. Chem. Commun. 2001;2440.
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See for example: Takano S., Inomata K., Sato T., Takahashi M., Ogasawara K. J. Chem. Soc., Chem. Commun. 1990;290.
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Kita Y., Furukawa A., Futamura J., Higuchi K., Ueda K., Fujioka H. Tetrahedron Lett. 41:2000;2133.
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Higuchi, K.4
Ueda, K.5
Fujioka, H.6
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0037163335
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For the stereoselective synthesis of other α-disubstituted cyclopentanones, see for example: and references cited therein
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For the stereoselective synthesis of other α-disubstituted cyclopentanones, see for example: Yoshida M., Sugimoto K., Ihara M. Tetrahedron. 58:2000;7839. and references cited therein.
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26
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0000780226
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The assignment of the absolute stereochemistries in the resolution step was based on the well-known ability of lipases to catalyse the acylation of the (R)-enantiomer of 2-substituted 4-hydroxycyclopent-2-enones. See for example:
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The assignment of the absolute stereochemistries in the resolution step was based on the well-known ability of lipases to catalyse the acylation of the (R)-enantiomer of 2-substituted 4-hydroxycyclopent-2-enones. See for example: Babiak K.A., Ng J.S., Dygos J.H., Weyker C.L., Wang Y.-F., Wong C.-H. J. Org. Chem. 55:1990;3377.
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27
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0020163034
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For the use of 4-hydroxycyclopent-2-enones as intermediates in the synthesis of prostaglandins see:
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For the use of 4-hydroxycyclopent-2-enones as intermediates in the synthesis of prostaglandins see: Harre M., Raddatz P., Walenta R., Winterfeld E. Angew. Chem., Int. Ed. Engl. 21:1982;480.
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For some other recent examples of the synthetic utility of 4-hydroxycyclopent-2-enones see:
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For some other recent examples of the synthetic utility of 4-hydroxycyclopent-2-enones see: West F.G., Gunawardena G.U. J. Org. Chem. 58:1993;2402.
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Rokach, J.7
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