Stereoselective total synthesis of (±)-Tochuinyl acetate and (±)-dihydrotochuinyl acetates

Tetrahedron

Volumn 54, Issue 28, 1998, Pages 8133-8140

  Srikrishna, A ^a   Reddy, T Jagadeeswar ^a  

^a INDIAN INSTITUTE OF SCIENCE   (India)

Author keywords

[No Author keywords available]

Indexed keywords

DIHYDROTOCHUINYL ACETATE; NATURAL PRODUCT; SESQUITERPENE DERIVATIVE; TOCHUINYL ACETATE; UNCLASSIFIED DRUG;

ACETYLATION; ARTICLE; MOLLUSC; NONHUMAN; OXIDATION; PRIORITY JOURNAL; REDUCTION; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS;

MOLLUSCA; STAPHYLOCOCCUS PHAGE 3A;

EID: 0032499962     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(98)00436-0     Document Type: Article

References (11)

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10. 9. A small sample of the acid 14 was converted into its ethyl ester 15b and established its structure by comparison of spectral data with that reported in the literature. Kametani, T.; Kawamura, K.; Tsubuki, M.; Honda, T. J. Chem. Soc., Perkin Trans. 1, 1988, 193.
11. 1H NMR spectrum of the ester 18, no detectable amount of signals due to the other epimer was observed indicating the high stereoselectivity of the alkylation reaction.