Cyclizative radical carbonylations of azaenynes by TTMSS and hexanethiol leading to α-silyl- and thiomethylene lactams. Insights into the E/Z stereoselectivities

Organic and Biomolecular Chemistry

Volumn 1, Issue 23, 2003, Pages 4262-4267

  Tojino, Mami ^a   Otsuka, Noboru ^a   Fukuyama, Takahide ^a   Matsubara, Hiroshi ^b   Schiesser, Carl H ^b   Kuriyama, Hiroki ^c   Miyazato, Hironari ^c   Minakata, Satoshi ^c   Komatsu, Mitsuo ^c   Ryu, Ilhyong ^a  

^a Osaka Prefecture University   (Japan)

^b UNIVERSITY OF MELBOURNE   (Australia)

^c OSAKA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CALCULATIONS; CARBONYLATION; COMPOSITION EFFECTS; FREE RADICALS; MOLECULAR ORIENTATION; PROBABILITY DENSITY FUNCTION; STEREOCHEMISTRY; SUBSTRATES; THERMODYNAMIC PROPERTIES;

AZAENYNES; CYCLIZATIVE RADICAL CARBONYLATIONS; FIVE-MEMBERED RINGS; HEXANETHIOL; LACTAMS; SEVEN-MEMBERED RINGS; STEREOSELECTIVITIES; TRIBUTYLIN HYDRIDE;

ORGANIC COMPOUNDS;

EID: 0348041600     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b309944j     Document Type: Article

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