A radical versatile synthesis of 2-iodomethylene cycloalkanols

Synlett

Volumn , Issue 1, 2000, Pages 83-85

  Chareyron, Maud ^a   Devin, Priscille ^a   Fensterbank, Louis ^a   Malacria, Max ^a  

^a SORBONNE UNIVERSITÉ   (France)

Author keywords

Cyclizations; Iodolysis; Radical reactions; Stereoselective synthesis; Tin

Indexed keywords

CARBONYL DERIVATIVE; CYCLOALKANOL DERIVATIVE; CYCLOHEXANOL DERIVATIVE; PENTANOL; TIN;

ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; STEREOCHEMISTRY; SYNTHESIS;

EID: 0033972361     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: None     Document Type: Article

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23. As pointed out by one referee, the gem-dimethyl group in 11 may also block the cyclization because the sp center attacked is nearly neopentyl. We thank the referee for this suggestion.