Voltammetric evidence for soluble FeS complexes in anoxic estuarine muds

Estuaries

Volumn 22, Issue 3, 1999, Pages 693-701

  Rickard, David ^a   Oldroyd, Anthony ^a   Cramp, Adrian ^a  

^a CARDIFF UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

UNITED KINGDOM;

ANOXIC CONDITIONS; ESTUARINE SEDIMENT; IRON SULFIDE; POREWATER; SEDIMENT CHEMISTRY;

LOUGHOR ESTUARY; UNITED KINGDOM; WALES;

EID: 0032701874     PISSN: 01608347     EISSN: None     Source Type: Journal    
DOI: 10.2307/1353056     Document Type: Article

References (22)

1. BERNER, R. A. 1970. Sedimentary pyrite formation. American Journal of Science 268:1-23.
2. BOTTRELL, S. H., P. K. K. LOUIE, R. C. TIMPE, AND S. B. HAWTHORNE. 1994. The use of stable isotope ratio analysis to assess selectivity of chemical analyses and extractions of forms of sulphur in coal. Fuel 73:1578-1582.
3. 2 and S(-II) porewaters of marine and freshwater sediments. Environmental Science and Technology 29:751-761.
4. BUFFLE, J., R. DE VITRE, D. PERRETT, AND G. G. LEPPARD. 1988. Combining field measurements for speciation in non-perturbable water samples, p. 99-124. In J. R. Kramer and H. E. Allen (eds.), Metal Speciation: Theory, Analysis and Application. Lewis Publishers Inc., Boca Raton, Florida.
5. 2+. Aquatic Geochemistry.
6. COTTON, F. A. AND G. WILKINSON. 1988. Advanced Inorganic Chemistry. John Wiley & Sons, New York.
7. CRAMP, A., J. THOMAS, AND P. J. BRABHAM. 1995. Hydrodynamics and sedimentation in the Loughor Estuary (Burry Inlet) -Observations from the present and recent past, p. 51-66. In J. Atkins (ed.), Burry Inlet and Loughor Estuary Symposium, State of the Estuary Report, Part 2. Proceedings of the Conference on the Burry Inlet and Loughor Estuary. Swansea City Council, Swansea.
8. 2, Fe(II), Mn(II), S(-II) and related species in anoxic waters. Pure and Applied Chemistry 60: 1535-1548.
9. DAVISON, W., J. BUFFLE, AND R. DE VITRE. In press. Voltammetric characterization of a dissolved iron sulphide species by laboratory and field studies. Analytica Chimica Acta.
10. DAVISON, W., N. PHILLIPS, AND B. J. TABNER. 1998. Soluble iron sulfide species in natural waters: Reappraisal of their stoichiometry and stability constants. Aquatic Science 377:193-203.
11. HELZ, G. R., J. M. CHARNOCK, D. J. VAUGHAN, AND C. D. GARNER. 1993. Multinuclearity of aqueous copper and zinc bisulfide complexes: An EXAFS investigation. Geochimica et Cosmochimica Acta 54:15-25.
12. HUETTEL, M., W. ZIEBIS, S. FORSTER, AND G. W. LUTHER, III. 1998. Advective transport affecting metal and nutrient distributions and interfacial fluxes in permeable sediments. Geochimica et Cosmochimica Acta 62:613-631.
13. LUTHER, III, G. W. AND T. G. FERDELMAN. 1993. Voltammetric characterization of iron(II) sulfide complexes in laboratory solutions and in marine waters and porewaters. Environmental Science and Technology 27:1154-1162.
14. LUTHER, III, G. W., D. RICKARD, S. M. THEBERGE, AND A. OLDROYD. 1996. Determination of metal (bisulfide) stability constants of Mn, Fe, Co, Ni, Cu, and Zn by voltammetric methods. Environmental Science and Technology 30:671-679.
15. MEITES, L. 1965. Polarographic Techniques, 2nd edition. Wiley Interscience, New York.
16. RICKARD, D. 1975. Kinetics and mechanism of pyrite formation at low temperatures. American Journal of Science 275:636-652.
17. RICKARD, D. 1995. Kinetics of FeS precipitation: 1. Competing reaction mechanisms. Geochimica et Cosmochimica Acta 59:4367-4380.
18. 2S oxidation of iron (II) monosulfide in aqueous solutions between 25°C and 125°C: The mechanism. Geochimica et Cosmochimica Acta 61:135-147.
19. RICKARD, D., M. A. A. SCHOONEN, AND G. W. LUTHER, III. 1995. The chemistry of iron sulfides in sedimentary environments, p. 168-193. In V. Vairavamurthy and M. A. A. Schoonen (eds.), Geochemical Transformations of Sedimentary Sulfur. American Chemical Society, Washington, D.C.
20. 2 below 100°C. Geochimica et Cosmochimica Acta 55:1495-1504.
21. THEBERGE, S. AND G. W. LUTHER, III. 1997. Determination of the electrochemical properties of a soluble aqueous FeS species present in sulfidic solutions. Aquatic Geochemistry 3:191-211.
22. WILKINS, R. T. AND H. L. BARNES. 1996. Pyrite formation by reactions of iron monosulfides with dissolved inorganic and organic sulfur species. Geochimica et Cosmochimica Acta 60:4167-4179.