Investigation of the effect of water complexes in the determination of peroxy radical ambient concentrations: Implications for the atmosphere

Journal of Geophysical Research: Atmospheres

Volumn 108, Issue 1, 2003, Pages

  Reichert, L ^a   Andres Hernandez M D ^a   Stobener D ^a   Burkert, J ^a   Burrows, J P ^a  

^a UNIVERSITY OF BREMEN   (Germany)

Author keywords

Chemical amplification; Peroxy radicals; Water effect

Indexed keywords

ATMOSPHERIC CHEMISTRY; PEROXY RADICAL; WATER VAPOR;

EID: 0347342420     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2002jd002152     Document Type: Article

References (50)

1. 2O) radical complex, J. Phys. Chem. A, 102, 1899-1902, 1998.
2. Aloisio, S., and J. S. Francisco, Complexes or hydroxyl and hydroperoxyl radical with formaldehyde, acetaldehyde, and acetone, J. Phys. Chem. A, 104, 3211 3224, 2000.
3. 2O complex, J. Phys. Chem. A, 104, 6597-6601, 2000.
4. Allen, T. L., W. H. Fink, and D. H. Volman, Theoretical studies of the mechanism of the gas phase reaction of the hydroperoxy radical with carbon monoxide to form hydroxyl radical and carbon dioxide, J. Phys. Chem., 100, 5299 5302, 1996.
5. Andrés Hernández, M. D., J. Burkert, L. Reichert, D. Stöbener, J. Meyer-Arnek, R. R. Dickerson, B. G. Doddridge, and J. P. Burrows, Marine boundary layer peroxy radical chemistry during the AEROSOLS99 campaign: Measurements and analysis, J. Geophys. Res., 106, 20,833-20,846, 2001.
6. Ayers, G. P., R. W. Gillett, H. Granek, C. de Serves, and R. A. Cox, Formaldehyde production in clean marine air, Geophys. Res. Lett., 24, 401-404, 1997.
7. Bacic, Z., and R. E. Miller, Molecular clusters: Structure and dynamics of weakly bound systems, J. Phys. Chem., 100, 12,945-12,959, 1996.
8. Burkert, J., M. D. Andrés Hernández, D. Stöbener, M. Weißenmeyer, and J. P. Burrows, Peroxy radical and related trace gases measurements in the boundary layer above the Atlantic Ocean, J. Geophys. Res., 106, 5457-5477, 2001.
9. 2 radical studied by laser magnetic resonance spectroscopy, Proc. R. Soc. London, Ser. A, 368, 463-481, 1979.
10. Cantrell, C. A., and D. H. Stedman, A possible technique for the measurement of atmospheric peroxy radicals, Geophys. Res. Lett., 9, 846-849, 1982.
11. Cantrell, C. A., A. Zimmer, and G. S. Tyndall, Absorption cross sections for water vapour from 183 to 193 nm, Geophys. Res. Lett., 24, 2195-2198, 1997.
12. Carlon, H. R., Phase transition changes in the molecular absorption coefficient of water in the infrared: Evidence for clusters, Appl. Opt., 17(20), 3192 3193, 1978.
13. Carpenter, L. J., P. S. Monks, B. J. bandy, S. A. Penkett, I. E. Galbally, and C. P. Meyer, A study of peroxy radicals and ozone photochemistry at coastal sites in the Northern and Southern Hemispheres, J. Geophys. Res., 102, 25,417-25,427, 1997.
14. Carver, G. D., P. D. Brown, and O. Wild, The ASAD atmospheric chemistry integration package and chemical reaction database, Comput. Phys. Commun., 105, 197-215, 1997.
15. Clemitshaw, K., et al., Peroxy radical initiative for measurements in the environment, PRIME, final report, Eur. Union, Brussels, 2001.
16. 2 in the gas phase, J. Phys. Chem., 83, 2560-2569, 1979.
17. Curtis, A. R. and W. P. Sweetenham, FACSIMILE Release H User's Manual, Comput. Sci. and Syst. Div., Harwell Lab., Oxfordshire, UK, 1985.
18. Crutzen, P. J., and P. H. Zimmermann, The changing photochemistry of the troposphere, Tellus, 43AB, 136-151, 1991.
19. Davis, D. D., W. A. Payne, and L. J. Stief, The hydroperoxyl radical in atmospheric chemical dynamics: Reaction with carbon monoxide, Science, 179, 280-283, 1973.
20. Goldman, N., R. S. Fellers, C. Leforestier, and R. J. Saykally, Water dimers in the atmosphere: Equilibrium constant for water dimerization from the VRT(ASP-W) potential surface, J. Phys. Chem., 105, 515-519, 2001.
21. 2 in the gas phase, J. Chem. Phys., 8, 3682-3683, 1975.
22. 2 and first results, Int. J. Mass Spectrom., 213, 91-99, 2002.
23. x measurements, Anal. Chem., 63, 2048-2057, 1991.
24. Hayman, G. D., J. Henshaw, and M. E. Jenkin, Numerical Model of the Calibration Source of a PERCA Instrument, AEA Technol., Culham, U. K., 1997.
25. Heitlinger, M., Untersuchungen zur Messung von Peroxiradikalen mittels chemischer Verstärkung, Ph.D. thesis, Univ. of Wuppertal, Wuppertal, 1997.
26. Hofzumahaus, A., et al., Reply, Geophys. Res. Lett., 24, 3039-3040, 1997.
27. 2 radical in the gas phase, J. Chem. Phys., 56, 4426-4432, 1972.
28. 4 surfaces, J. Phys. Chem. A, 101, 10,000-10,011, 1997.
29. Jenkin, M., and K. C. Klemitshaw, Ozone and other secondary photochemical pollutants: Chemical processes governing their formation in the planetary boundary layer, Atmos. Environ., 34, 2499-2527, 2000.
30. 2 disproportionations, J. Phys. Chem., 88, 2082-2091, 1984.
31. Lightfoot, P. D., R. A. Cox, J. N. Crowley, M. Destriau, G. D. Hayman, M. E. Jenkin, G. K. Moortgat, and F. Zabel, Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry, Atmos. Environ., 26A, 1805, 1992.
32. 3, J. Phys. Chem., 84, 813-817, 1980.
33. 2O, J. Phys. Chem., 85, 2833-2834, 1981.
34. 2 with water, J. Phys. Chem., 100, 19,911-19,916, 1996.
35. Mihele, C. M., and D. R. Hastie, The sensitivity of the radical amplifier to ambient water vapour, Geophys. Res. Lett., 25, 1911-1913, 1998.
36. Mihele, C. M., M. Mozurkewich, and D. R. Hastie, Radical loss in a chain reaction of CO and NO in the presence of water: Implications for the radical amplifier and atmospheric chemistry, Int. J. Chem. Kinet., 31, 145 152, 1999.
37. Monks, P. S., L. J. Carpenter, S. A. Penkett, and G. P. Ayers, Night-time peroxy radical chemistry in the remote marine boundary layer over the Southern ocean, Geophys. Res. Lett., 23, 535-538, 1996.
38. Reichert, L., Untersuchung des Wassereffektes eines Peroxyradikal-Detektors, M.S. thesis, Univ. of Bremen, Bremen, Germany, 2000.
39. Reiner, T., M. Hanke, and F. Arnold, Atmospheric peroxy radical measurements by ion molecule reaction-mass spectrometry: A novel analytical method using amplifying chemical conversion to sulphuric acid, J. Geophys. Res., 102, 1311-1326, 1997.
40. Salisbury, G., P. S. Monks, S. Bauguitte, B. J. Bandy, and S. A. Penkett, A seasonal comparison of the ozone photochemistry in clean and polluted air masses at Mace Head, Ireland, J. Atmos. Chem., 41, 163-187, 2002.
41. 2 + M, J. Phys. Chem., 88, 1566-1571, 1984.
42. 2 reactions at 298 K, J. Phys. Chem., 86, 1236-1240, 1982.
43. Stedman, D. H., J. G. Walega, C. A. Cantrell, J. P. Burrows, and G. Tyndall, Chemistry of Multiphase Atmospheric Systems, NATO ASI Ser., Ser. G., vol. 6, edited by W. Jaeschke, pp. 60-95, Springer-Verlag, New York, 1985.
44. 2 photolysis at 185 nm, J. Geophys. Res., 100, 18,811-18,816, 1995.
45. 2 measurements, M.S. thesis, Univ. of Bremen, Germany, April 1999. (Available as http://www.iup.physik.uni-bremen.de/troposphere/Publications.html).
46. Volz-Thomas, A., et al., Peroxy Radical Intercomparison Exercise: A formal comparison of methods for ambient measurements of peroxy radicals, Ber. des Forshung. Juelich, 3597, ISSN 0944-2952, Inst. für Chem. und Dyn. der Geosphäre-2, 1998.
47. Volz-Thomas, A., et al., Peroxy Radical Intercomparison Exercise II, Final Rep. to the EU, ISSN 0944-2952, 1999.
48. Wagner, V., C. Schiller, and H. Fischer, Formaldehyde measurements in the marine boundary layer of the Indian Ocean during the 1999 INDOEX cruise of the RV Ronald H. Brown, J. Geophys. Res., 106(D22), 28,529-28,538, 2001.
49. Weller, R., O. Schrems, A. Boddenberg, S. Gaeb, and M. Gautrouis, Meridional distribution of hydroxyperoxides and formaldehyde in the boundary layer of the Atlantic (48°N-35°S) measured during the ALBATROSS campaign, J. Geophys. Res., 105, 14,401-14,412, 2000.
50. 2 results, Phys. Chem., 76, 1586-1593, 1972.