Marine boundary layer peroxy radical chemistry during the AEROSOLS99 campaign: Measurements and analysis

Journal of Geophysical Research Atmospheres

Volumn 106, Issue D18, 2001, Pages 20833-20846

  Andrés Hernández, Maria Dolores ^a   Burkert, Jörn ^a   Reichert, Lars ^a   Stöbener, Dirk ^a   Meyer Arnek, Julian ^a   Burrows, John P ^a   Dickerson, R R ^b   Doddridge, B G ^b  

^a UNIVERSITY OF BREMEN   (Germany)

^b UNIVERSITY OF MARYLAND   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BIOMASS BURNING; BOUNDARY LAYER; DIURNAL VARIATION; MARINE ATMOSPHERE; PEROXY RADICAL;

ATLANTIC OCEAN; INDIAN OCEAN;

EID: 0034781232     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2001jd900113     Document Type: Article

References (59)

1. Allan, B.J., G. McFiggans, J.M.C. Plane, and H. Coe, Observations of iodine monoxide in the remote marine boundary layer, J. Geophys. Res., 105, 14,363-14,370, 2000.
2. 2O) radical complex, J. Phys. Chem. A, 102, 1899-1902, 1998.
3. Baldy, S., G. Ancellet, M. Bessafi, A. Badr, and D. Lan Sun Luk, Field observations of the vertical distribution of tropospheric ozone at the island of Reunion (southern tropics), J. Geophys. Res., 101,23,835-23,849, 1996.
4. Bates, T.S., P.K. Quinn, D.J. Coffman, J.E. Johnson, T.L. Miller, D.S. Covert, A. Wiedensohler, S. Leinert, A. Nowak, and C. Neus, Regional physical and chemical properties of the marine boundary layer aerosol across the Atlantic during Aerosols99: An overview, J. Geophys. Res., this issue.
5. Blindauer, C, V. Rozanov, and J.P. Burrows, Actinic flux and photolysis frequency comparison computations using the model PHOTOGT, J. Atmos. Chem., 24, 1-21, 1996.
6. Brauers, T., M. Hausmann, A. Bister, A. Kraus, and H.P. Dorn, OH radicals in the Boundary Layer of the Atlantic Ocean,1, Measurements by Long-Path Laser Absorption Spectroscopy, J. Geophys. Res., 106, 1399-1414, 2001.
7. Bremaud, P., J.F. Taupin, A.M. Thompson, and N. Chaumerliac, Ozone nighttime recovery in the marine boundary layer: Measurement and simulation of the ozone diurnal cycle at Reunion Island, J. Geophys. Res., 103, 3463-3473, 1998.
8. Buchwitz, M., A correlated-k distribution scheme for overlapping gases suitable for retrieval of atmospheric constituents from moderate resolution radiance measurements in the visible/near-infrared spectral region, J. Geophys. Res., 105, 15,247-15,261, 2000.
9. Burkert, J., T. Behmann, M.D. Andrés Hernández, D. Stöbener, M. Weißenmeyer, D. Perner, and J.P. Burrows, Measurements of peroxy radicals in a forested area of Portugal, Chemosphere, in press, 2001a.
10. Burkert, J., M.D. Andrés Hernández, D. Stöbener, M. Weißenmeyer, and J.P. Burrows, Peroxy radical and related trace gases measurements in the boundary layer above the Atlantic Ocean, J. Geophys. Res., 106, 5457-5477, 2001b.
11. Burrows, J.P. et al., The global ozone monitoring experiment (GOME): Mission concept and first scientific results, J. Atmos. Sci., 56, 151-175, 1999.
12. Carpenter, L.J., W.T. Sturges, S.A. Penkett, P.S. Liss, B. Alicke, K. Hebestreit, and U. Platt, Short-lived alkyl iodides and bromides at Mace Head, Ireland: Links to biogenic sources and halogen oxide production, J. Geophys. Res., 104, 1679-1689, 1999.
13. Carver, G.D., P.D. Brown, and O. Wild, The ASAD atmospheric chemistry integration package and chemical reaction database, Comput. Phys. Commun., 105, 197-215, 1997.
14. Clemitshaw K.C., L.J. Carpenter, S.A. Penket and M.E. Jenkin, A calibrated peroxy radical chemical amplifier (PERCA) instrument for ground-based tropospheric measurements, J. Geophys. Res., 102, 25,405-25,416, 1997.
15. Crutzen, P.J., A discussion of the chemistry of some minor constituents in the stratosphere and troposphere, Pure Appl. Geophys., 106-108, 1385-1399, 1973.
16. Crutzen, P.J., Ozone in the troposphere, in Composition, Chemistry and Climate of the Atmosphere, edited by H.B. Singh, pp. 349-393, Van Nostrand Reinhold, New York, 1995.
17. Crutzen, P.J., and P.H. Zimmermann, The changing photochemistry of the troposphere, Tellus, Ser. AB, 43, 136-151, 1991.
18. Davis, D., J. Crawford, S. Liu, S. McKeen, A. Bandy, D. Thornton, F. Rowland, and D. Blake, Potential impact of iodine on tropospheric levels of ozone and other critical oxidants, J. Geophys. Res., 101, 2135-2147, 1996.
19. DeMore, W.B., S.P. Sander, D.M. Golden, R.F. Hampson, M.J. Kurylo, C.J. Howard, A.R. Ravishankara, C.E. Kolb, and M.J. Molina, Chemical kinetics and photochemical data for use in stratospheric modeling, Evaluation number 12, JPL Publ.97-4, 1997.
20. Dickerson, R.R., K.P. Rhoads, T.P. Carsey, S.J. Oltmans, J.P. Burrows, and P.J. Crutzen, Ozone in the remote marine boundary layer: A possible role for halogens, J. Geophys. Res., 104, 21,385-21,395, 1999.
21. Draxler, R.R., Hybrid Single-Particle Lagrangian Integrated Trajectories (HY-SPLIT): Version 3.0. user's guide and model description, Tech. Rep. ERL ARL-195, Natl. Oceanic and Atmos. Admin., Silver Spring, Md., 1992.
22. Gautrois, M., R. Koppmann, F.J. Johnen, C. Plass-Dülmer, A. Reiner, G. Leckebusch, and P. Speth, The distribution of nonmethane hydrocarbons and halocarbons over the Atlantic, J. Geophys. Res., in press, 2001.
23. Graedel, T.E., and W.C. Keene, Tropospheric budget of reactive chlorine, Global Biogeochem. Cycles, 9, 47-77, 1995.
24. x measurements, Anal. Chem., 63, 2048-2057, 1991.
25. Heikes, B., M. Lee, D. Jacob, R. Talbot, J. Bradshaw, H. Singh, D. Blake, B. Anderson, H. Fuelberg, and A.M. Thompson, Ozone, hydroperoxides, oxides of nitrogen, and hydrocarbon budgets in the marine boundary layer over the South Atlantic, J. Geophys. Res., 101, 24,221-24,238, 1996.
26. Hertel, O., J. Christensen, and O. Hov, Modelling of the end products of the chemical decomposition of DMS in the marine boundary layer, Atmos. Environ., 28, 2431-2449, 1994.
27. Hess, M., P. Koepke, and I. Schult, Optical Properties of Aerosols and Clouds: The software package OPAC, Bull. Am. Meteorol. Soc., 79, 831-844, 1998.
28. 1D) and primary OH production rates over the Atlantic Ocean between 50°N and 30°S, J. Atmos. Chem., 15, 283-298, 1992.
29. Jenkin, M.E., and K.C. Clemitshaw, Ozone and other secondary photochemical pollutants: Chemical processes governing their formation in the planetary boundary layer, Atmos. Environ., 34, 2499-2527, 2000.
30. Johnson, J.E., R.H. Gammon, J. Larsen, T.S. Bates, S.J. Oltmans, and J.C. Farmer, Ozone in the marine boundary layer over the Pacific and Indian Oceans: Latitudinal gradients and diurnal cycles, J. Geophys. Res., 95, 11,847-11,856, 1990.
31. Keene, W.C., A.A.P. Pszenny, D.J. Jacob, R.A. Duce, J.N. Galloway, J.J. Schultz-Tokos, H. Sievering, and J.F. Boatman, The geochemical cycling of reactive chlorine through the marine troposphere, Global Biogeochem. Cycles, 4, 407-430, 1990.
32. Koppmann, R., T. Brauers, F.J. Hohen, C. Plass, and J. Rudolph, The distribution of light non methane hydrocarbons over the Mid-Atlantic: Results of the Polarstem cruise ANT VII/1, J. Atmos. Chem., 15, 215-234, 1992.
33. Lal, S., M. Naja, and A. Jayaraman, Ozone in the marine boundary layer over the tropical Indian Ocean, J. Geophys. Res., 103, 18,907-18,917, 1998.
34. Lelieveld, J., et al., The Indian Ocean Experiment: Widespread air pollution from South and Southeast Asia, Science, 291, 1031-1036, 2001.
35. Lightfoot, P.D., R.A. Cox, J.N. Crowley, M. Destriau, G.D. Hayman, M.E. Jenkin, G.K. Moortgat, and F. Zabel, Organic peroxy radicals: Kinetics, spectroscopy and tropospheric chemistry, Atmos. Environ., 26A, 1805, 1992.
36. McFiggans, G., J.M.C. Plane, B.J. Allan, L.J. Carpenter, H. Coe, and C. O'Dowd, A modeling study of iodine chemistry in the marine boundary layer, J. Geophys. Res., 105, 14,371-14,385, 2000.
37. Mihele, C.M., and D.R. Hastie, The sensitivity of the radical amplifier to ambient water vapour, Geophys. Res. Lett., 25, 1911-1913, 1998.
38. Mihele, C.M., M. Mozurkewich, and D.R Hastie, Radical loss in a chain reaction of CO and NO in the presence of water: Implications for the radical amplifier and atmospheric chemistry, Int. J. Chem. Kinet., 31, 145-152, 1999.
39. Monks, P.S., L.J. Carpenter, and S.A. Penkett, Night-time peroxy radical chemistry in the remote marine boundary layer over the Southern ocean, Geophys. Res. Lett., 23, 535-538, 1996.
40. Monks, P.S., L.J. Carpenter, S.A. Penkett, G.P. Ayers, R.W. Gillett, I.E. Galbally, and C.P. Meyer, Fundamental ozone photochemistry in the remote marine boundary layer: The Soapex experiment, measurement and theory, Atmos. Environ., 32, 3647-3664, 1998.
41. Monks, P.S., G. Salisbury, G. Holland, S.A. Penkett, and G.P. Ayers, A seasonal comparison of ozone photochemistry in the remote marine boundary layer, Atmos. Environ., 34, 2547-2561, 2000.
42. Paluch, I.R., S. Mckeen, D.H. Lenschow, R.D. Schillawski, and G.L. Kok, Evolution of the subtropical marine boundary layer: Photochemical ozone loss, J. Atmos. Sci., 52, 2967-2976, 1995.
43. Parsons, R.L., and R.R. Dickerson, NOAA Ship Ronald H. Brown: World global climate study, Sea Technol, 40, 39-45, 1999.
44. Perner, D., T. Arnold, J. Crowley, T. Klüpfel, M. Martinez, and R. Seuwen, The measurement of active chlorine in the atmosphere by chemical amplification, J. Atmos. Chem., 34, 9-2, 1999.
45. Reichert, L., Untersuchung des Wassereffektes eines Peroxyradikal-Detektors, M.Sc. thesis, Univ. of Bremen, Bremen, Germany, April 2000.
46. Rhoads, K.P., P. Kelley, R.R Dickerson, T. Carsey, M. Farmer, S.J. Oltmans, D. Savoie, and J.M. Prospero, The composition of the troposphere over the Indian Ocean during the monsoonal transition, J. Geophys. Res., 102, 18,981-18,995, 1997.
47. Richter, A., F. Wittrock, M. Eisinger, and J.P. Burrows, GOME Observations of Tropospheric BrO in Northern Hemispheric Spring and Summer 1997, Geophys. Res. Lett., 25, 2683-2686, 1998.
48. Rudolph, J., and F.J. Johen, Measurements of light atmospheric hydrocarbons over the Atlantic in regions of low biological activity, J. Geophys. Res., 95, 20,583-20,591, 1990.
49. Sander, R., and P.J. Crutzen, Model study indicating halogen activation and ozone destruction in polluted air masses transported to the sea, J. Geophys. Res., 101, 9121-9138, 1996.
50. Sander, R., R. Vogt, G.W. Harris, and P.J. Crutzen, Modeling the chemistry of ozone, halogen compounds, and hydrocarbons in the arctic troposphere during spring, Tellus, Ser. B, 49, 522-532, 1997.
51. 2 photolysis at 185nm. J. Geophys. Res., 100, 18,811-18,816, 1995.
52. Shettle, E.P., and R.W. Fenn, Models of atmospheric aerosols and their optical properties, AGARD Conf. Proc., 183, ADA028-615, 1976.
53. 2-Messungen in Außenluft, M.Sc. thesis, Univ. of Bremen, Bremen, Germany, July 1999.
54. Thompson, A.M., B.G. Doddridge, J.C. Witte, R.D. Hudson, W.T. Luke, J.E. Johnson, B.J. Johnson, S.J. Oltmans, and R. Weller, A tropical Atlantic paradox: Shipboard and satellite views of a tropospheric ozone maximum and wave-one in January-February 1999, Geophys. Res. Lett., 27, 3317-3320, 2000.
55. Voss, K.J., E.J. Welton, P.K. Quinn, R. Frouin, and M. Reynolds, Aerosol optical depth Measurements during the Aerosols99 experiment, J. Geophys. Res., this issue.
56. Wagner, T., and U. Platt, Satellite mapping of enhanced BrO concentrations in the troposphere, Nature, 395, 486-490, 1998.
57. Weller, R., O. Schrems, A. Boddenberg, S. Gaeb, and M. Gautrouis, Meridional distribution of hydroxiperoxides and formaldehyde in the boundary layer of the Atlantic (48°N-35°S) measured during the ALBATROSS campaign, J. Geophys. Res., 105, 14,401-14,412, 2000.
58. Wittrock, F., R. Müller, A. Richter, H. Bovensmann, and J.P. Burrows, Measurements of Iodine monoxide (IO) above Spitsbergen, Geophys. Res. Lett., 27, 1471-1474, 2000.
59. Yin, F., D. Grosjean, and J.H. Seinfeld, Photooxidation of dimethyl sulphide and dimethyldisulfide, 1, Mechanism development, J. Atmos. Chem., 11, 309-364, 1990.