메뉴 건너뛰기




Volumn 45, Issue 3, 2004, Pages 527-529

Synthesis of C60 derivatives for photoaffinity labeling

Author keywords

[No Author keywords available]

Indexed keywords

AZIDE; AZIRIDINE DERIVATIVE; DIMETHYLFULLEROPYRROLIDINE; FUNCTIONAL GROUP; PHENYL GROUP; PYRROLIDINE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 0346363695     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.10.212     Document Type: Article
Times cited : (16)

References (30)
  • 20
    • 85030918315 scopus 로고    scopus 로고
    • Miyata, N.; Yamakoshi, Y.; Inoue, H.; Kojima, M.; Takahashi, K.; Iwata, N. In Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials; Kadish, K. M., Ruoff, R. S., Eds.; The Electrochemical Society, Inc.: Pennington, NJ, 1998; Vol. 6, pp 1227-1235
    • Miyata, N.; Yamakoshi, Y.; Inoue, H.; Kojima, M.; Takahashi, K.; Iwata, N. In Fullerenes: Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials; Kadish, K. M., Ruoff, R. S., Eds.; The Electrochemical Society, Inc.: Pennington, NJ, 1998; Vol. 6, pp 1227-1235.
  • 25
    • 85030933483 scopus 로고    scopus 로고
    • note
    • 60 (36 mg, 0.05 mmol) and D,L-alanine (9.2 mg, 0.10 mmol) in 1,2-dichlorobenzene (10 mL), acetaldehyde (11 mg, 0.25 mmol) was added and the mixture stirred at 120°C for 20 h. The reaction process was checked by HPLC [silica gel column, solvent: benzene-EtOAc (10:1)]. The reaction mixture was purified by silica gel column chromatography (hexane-benzene-EtOAc) to give brown solid 2 (9.0 mg, 0.011 mmol, y=22% ) as a cis- and trans-mixture.
  • 26
    • 85030926092 scopus 로고    scopus 로고
    • note
    • 3N was added. The products (cis- and trans-isomers) were separated by silica gel column chromatography (hexane-benzene-EtOAc) to give cis-5 (8.9 mg, 9.5 μmol, y=38% ) and trans-5 (13.3 mg, 14.2 μmol, y=57% ).
  • 27
    • 85030931327 scopus 로고    scopus 로고
    • note
    • 2) to give cis-9 (2.5 mg, 2.5 μmol, y=20% ) and trans-9 (5.6 mg, 5.6 μmol, y=44% ).
  • 28
    • 85030923534 scopus 로고    scopus 로고
    • note
    • -), 720.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.