Unique Guest-Inclusion Properties of a Breathing Ionic Crystal of K 3[Cr3O(OOCH)6(H2O) 3][α-SiW12O40]·16H2O

Chemistry - A European Journal

Volumn 9, Issue 23, 2003, Pages 5850-5857

  Uchida, Sayaka ^a   Mizuno, Noritaka ^a  

^a UNIVERSITY OF TOKYO   (Japan)

Author keywords

Host guest systems; Polyoxometalates; Selective sorption; Thermodynamics

Indexed keywords

COMPLEXATION; CRYSTALLIZATION; METHANE; MICROSTRUCTURE; MOLECULAR STRUCTURE; OXIDATION; POSITIVE IONS; SYNTHESIS (CHEMICAL); THERMAL EFFECTS; VACUUM APPLICATIONS;

IONIC CRYSTALS;

POTASSIUM;

ALCOHOL DERIVATIVE; ANION; CARBENE; CATION; CHROMIUM DERIVATIVE; ION; METAL DERIVATIVE; METHANE; METHANOL; NITROGEN; ORGANIC COMPOUND; OXYGEN DERIVATIVE; POLYMER; POTASSIUM DERIVATIVE; TUNGSTEN DERIVATIVE; WATER;

ADSORPTION; ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CRYSTAL STRUCTURE; CRYSTALLIZATION; DIPOLE; HOST GUEST SYSTEM; IONIZATION; MOLECULAR INTERACTION; MOLECULAR SIZE; OXIDATION; SURFACE CHARGE; SYNTHESIS; THERMODYNAMICS; VACUUM;

EID: 0346363227     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/chem.200304874     Document Type: Article

References (98)

1. a) S. M. Csicsery, Pure Appl. Chem. 1986, 56, 841;
2. b) A. Corma, Chem. Rev. 1995, 95, 559;
3. c) W. E. Farneth, R. J. Gorte, Chem. Rev. 1995, 95, 615;
4. d) R. A. van Santen, G. J. Kramer, Chem. Rev. 1995, 95, 637;
5. e) A. K. Cheetham, G. Férey, T. Loiseau, Angew. Chem. 1999, 111, 3466; Angew. Chem. Int. Ed. 1999, 38, 3268;
6. e) A. K. Cheetham, G. Férey, T. Loiseau, Angew. Chem. 1999, 111, 3466; Angew. Chem. Int. Ed. 1999, 38, 3268;
7. f) J. M. Thomas, Angew. Chem. 1999, 111, 3852; Angew. Chem. Int. Ed. 1999, 38, 3588.
8. f) J. M. Thomas, Angew. Chem. 1999, 111, 3852; Angew. Chem. Int. Ed. 1999, 38, 3588.
9. a) M. Fujita, Y. J. Kwon, S. Washizu, K. Ogura, J. Am. Chem. Soc. 1994, 116, 1151;
10. b) S. Kitagawa, M. Kondo, Bull. Chem. Soc. Jpn. 1998, 71, 1739;
11. c) J. S. Seo, D. Whang, H. Lee, S. I. Jun, J. Oh, Y. J. Jeon, K. Kim, Nature 2000, 404, 982;
12. d) M. Eddaoudi, D. B. Moler, H. Li, B. Chen, T. M. Reinke, M. O'Keeffe, O. M. Yaghi, Acc. Chem. Res. 2001, 34, 319;
13. e) B. Moulton, M. J. Zaworotko, Chem. Rev. 2001, 101, 1629;
14. f) B. Gomez-Lor, E. Gutierrez-Puebla, M. Iglesias, M. A. Monge, C. Ruiz-Valero, N. Snejko, Inorg. Chem. 2002, 41, 2429;
15. g) L. Pan, H. Liu, X. Lei, X. Huang, D. H. Plson, N. J. Turro, J. Li, Angew. Chem. 2003, 115, 560; Angew. Chem. Int. Ed. 2003, 42, 542.
16. g) L. Pan, H. Liu, X. Lei, X. Huang, D. H. Plson, N. J. Turro, J. Li, Angew. Chem. 2003, 115, 560; Angew. Chem. Int. Ed. 2003, 42, 542.
17. a) K. Endo, T. Sawaki, M. Koyanagi, K. Kobayashi, H. Masuda, Y. Aoyama, J. Am. Chem. Soc. 1995, 117, 8341;
18. b) T. Hertzsch, F. Budde, E. Weber, J. Hulliger, Angew. Chem. 2002, 114, 2385; Angew. Chem. Int. Ed. 2002, 41, 2282.
19. b) T. Hertzsch, F. Budde, E. Weber, J. Hulliger, Angew. Chem. 2002, 114, 2385; Angew. Chem. Int. Ed. 2002, 41, 2282.
20. a) M. Albrecht, M. Lutz, A. L. Spek, G. van Koten, Nature 2000, 406, 970;
21. b) M. Albrecht, R. A. Gossage, M. Lutz, A. L. Spek, G. van Koten, Chem. Eur. J. 2000, 6, 1431;
22. c) K. M. Padden, J. F. Krebs, C. E. MacBeth, R. C. Scarrow, A. S. Borovik, J. Am. Chem. Soc. 2001, 123, 1072.
23. a) V. A. Russell, C. C. Evans, W. Li, M. D. Ward, Science 1997, 276, 575;
24. b) C. J. Kepert, D. Hesek, P. D. Beer, M. J. Rosseinsky, Angew. Chem. 1998, 110, 3335; Angew. Chem. Int. Ed. 1998, 37, 3158;
25. b) C. J. Kepert, D. Hesek, P. D. Beer, M. J. Rosseinsky, Angew. Chem. 1998, 110, 3335; Angew. Chem. Int. Ed. 1998, 37, 3158;
26. c) A. J. Fletcher, E. J. Cussen, T. J. Prior, M. J. Rosseinsky, C. J. Kepert, K. M. Thomas, J. Am. Chem. Soc. 2001, 123, 10001;
27. d) M. Edgar, R. Mitchell, M. Z. Slawin, P. Lightfoot, P. A. Wright, Chem. Eur. J. 2001, 7, 5168;
28. e) R. Kitaura, K. Fujimoto, S. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 141; Angew. Chem. Int. Ed. 2002, 41, 133;
29. e) R. Kitaura, K. Fujimoto, S. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 141; Angew. Chem. Int. Ed. 2002, 41, 133;
30. f) E. J. Cussen, J. B. Claridge, M. J. Rosseinsky, C. J. Kepert, J. Am. Chem. Soc. 2002, 124, 9574.
31. a) O. M. Yaghi, G. Li, H. Li, Nature 1995, 378, 703;
32. b) K. Biradha, Y. Hongo, M. Fujita, Angew. Chem. 2002, 114, 3545; Angew. Chem. Int. Ed. 2002, 41, 3395.
33. b) K. Biradha, Y. Hongo, M. Fujita, Angew. Chem. 2002, 114, 3545; Angew. Chem. Int. Ed. 2002, 41, 3395.
34. a) M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34;
35. a) M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34;
36. b) T. Okuhara, N. Mizuno, M. Misono, Adv. Catal. 1996, 41, 113;
37. c) "Polyoxometalates" (Ed.: C. L. Hill): Chem. Rev. 1998, 98, 1;
38. d) R. Neumann, Prog. Inorg. Chem. 1998, 47, 317.
39. a) M. Misono, N. Mizuno, K. Katamura, A. Kasai, Y. Konishi, K. Sakata, T. Okuhara, Y. Yoneda, Bull. Chem. Soc. Jpn. 1982, 55, 400;
40. b) J. G. Highfield, J. B. Moffat, J. Catal. 1985, 95, 108;
41. c) J. G. Highfield, J. B. Moffat, J. Catal. 1986, 98, 245;
42. d) T. Okuhara, S. Tatemateu, K. W. Lee, M. Misono, Bull. Chem. Soc. Jpn. 1989, 62, 717;
43. e) J. B. Moffat, Metal-Oxygen Clusters, Kluwer Academic/Plenum, New York, 2001, chap. 7.
44. a) N. Mizuno, M. Misono, Chem. Lett. 1987, 267;
45. b) T. Okuhara, T. Nishimura, M. Misono, Chem. Lett. 1995, 155;
46. c) Y. Yoshinaga, K. Seki, T. Nakato, T. Okuhara, Angew. Chem. 1997, 109, 2946; Angew. Chem. Int. Ed. Engl. 1997, 36, 2833.
47. c) Y. Yoshinaga, K. Seki, T. Nakato, T. Okuhara, Angew. Chem. 1997, 109, 2946; Angew. Chem. Int. Ed. Engl. 1997, 36, 2833.
48. a) M. Hölscher, U. Englert, B. Zibrowius, W. F. Hölderich, Angew. Chem. 1994, 106, 2552; Angew. Chem. Int. Ed. Engl. 1994, 33, 2491;
49. a) M. Hölscher, U. Englert, B. Zibrowius, W. F. Hölderich, Angew. Chem. 1994, 106, 2552; Angew. Chem. Int. Ed. Engl. 1994, 33, 2491;
50. b) A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, F. Peters, C. Menke, J. Meyer, Angew. Chem. 1997, 109, 500; Angew. Chem. Int. Ed. Engl. 1997, 36, 484;
51. b) A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, F. Peters, C. Menke, J. Meyer, Angew. Chem. 1997, 109, 500; Angew. Chem. Int. Ed. Engl. 1997, 36, 484;
52. c) M. L. Khan, E. Yohannes, D. Powell, Inorg. Chem. 1999, 38, 212;
53. d) D. Hagrman, P. J. Hagrman, J. Zubieta, Angew. Chem. 1999, 111, 3359; Angew. Chem. Int. Ed. 1999, 38, 3165;
54. d) D. Hagrman, P. J. Hagrman, J. Zubieta, Angew. Chem. 1999, 111, 3359; Angew. Chem. Int. Ed. 1999, 38, 3165;
55. e) J. H. Son, H. Choi, Y. U. Kwon, J. Am. Chem. Soc. 2000, 122, 7432;
56. f) A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, P. Kögerler, C. Rosu, E. Beckman, Angew. Chem. 2001, 113, 4158; Angew. Chem. Int. Ed. 2001, 40, 4034.
57. f) A. Müller, E. Krickemeyer, H. Bögge, M. Schmidtmann, P. Kögerler, C. Rosu, E. Beckman, Angew. Chem. 2001, 113, 4158; Angew. Chem. Int. Ed. 2001, 40, 4034.
58. a) V. W. Day, W. G. Klemperer, O. M. Yaghi, J. Am. Chem. Soc. 1989, 111, 5959;
59. b) M. I. Khan, J. Zubieta, Angew. Chem. 1994, 106, 784; Angew. Chem. Int. Ed. Engl. 1994, 33, 760;
60. b) M. I. Khan, J. Zubieta, Angew. Chem. 1994, 106, 784; Angew. Chem. Int. Ed. Engl. 1994, 33, 760;
61. c) Y. Hayashi, F. Müller, Y. Lin, S.M. Miller, O. P. Anderson, R. G. Finke, J. Am. Chem. Soc. 1997, 119, 11401.
62. S. Uchida, M. Hashimoto, N. Mizuno, Angew. Chem. 2002, 114, 2938; Angew. Chem. Int. Ed. 2002, 41, 2814.
63. S. Uchida, M. Hashimoto, N. Mizuno, Angew. Chem. 2002, 114, 2938; Angew. Chem. Int. Ed. 2002, 41, 2814.
64. A. Kobayashi, Y. Sasaki, Bull. Chem. Soc. Jpn. 1975, 48, 885.
65. a) B. N. Figgis, G. B. Robertson, Nature 1965, 205, 694;
66. +. As far as we know, the crystal structure of 1 is the first case of the formate analogue.
67. +) and van der Waals radii (other atoms) of the constituent ions.
68. 2O (4) are presented in the Experimental Section. 1, 3, and 4 gave identical XRD patterns (as shown in Figure S-1 in the Supporting Information), a result indicating that the preservation of the charge and shape of the constituent ions is requisites for the construction of the channeled structure.
69. A. Tézé, G. Hervé, Inorg. Syn. 1990, 27, 93.
70. M. K. Johnson, D. B. Powell, R. D. Cannon, Spectrochim. Acta 1981, 37A, 995.
71. II configuration appeared at 440 and 580 nm, respectively.
72. G. C. Pimentel, A. L. McClellan, The Hydrogen Bond, W. H. Freeman and Company, San Francisco, 1960, chap. 3.
73. +. The channel volume of this complex was 17% of the unit cell, which was comparable to the ideal closest-packing model of 2 (20%). The details will be described in a subsequent article.
74. 0=0.8 in Figure 3 and the Z value was 4.
75. 1=0.0480, wR2=0.0480. See ref. [12] for further information.
76. S. J. Gregg, K. S. W. Sing, Adsorption, Surface Area and Porosity, Academic Press, London, 1982, p. 237.
77. a) R. W. Mooney, A. G. Keenan, L. A. Wood, J. Am. Chem. Soc. 1952, 74, 1367;
78. b) R. M. Barrer, D. M. MacLeod, Trans. Faraday Soc. 1954, 50, 980;
79. c) S. Yamanaka, F. Kanamaru, M. Koizumi, J. Phys. Chem. 1974, 78, 42.
80. A. L. McClellan, Tables of Experimental Dipole Moments, W. H. Freeman and Company, San Francisco, 1963.
81. a) D. Li, K. Kaneko, Chem. Phys. Lett. 2001, 335, 50;
82. b) R. Kitaura, K. Fujimoto, S. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 141; Angew. Chem. Int. Ed. 2002, 41, 133.
83. b) R. Kitaura, K. Fujimoto, S. Noro, M. Kondo, S. Kitagawa, Angew. Chem. 2002, 114, 141; Angew. Chem. Int. Ed. 2002, 41, 133.
84. a) C. Tsiao, D. R. Corbin, C. Dybowski, J. Am. Chem. Soc. 1990, 112, 7140;
85. b) E. J. Munson, A. A. Kheir, N. D. Lazo, J. F. Haw, J. Phys. Chem. 1992, 96, 7740.
86. Charges of -2 and -0.5 were used for the oxygen atoms of the polyoxometalate and macrocation, respectively, in the calculation of the ion-dipole interaction with water molecules. The dipole moment of the water molecule found in ref. [26] was 1.85 debye.
87. P. W. Atkins, Physical Chemistry, Oxford University Press, Oxford, 1990, chap. 22.
88. -1).
89. P. W. Atkins, Physical Chemistry, Oxford University Press, Oxford, 1990, chap. 29.
90. -1 was obtained.
91. L. Glasser, H. D. B. Jenkins, J. Am. Chem. Soc. 2000, 122, 632.
92. -1 at 298 K (as shown in Figure 6b) and the volume occupied by one molecule of the water of crystallization in 1 was close to that of liquid water. Therefore, the chemical potential of the included guests may be close to that in the liquid state. A similar treatment has been reported for clays. See ref. [36].
93. a) A. Delville, Langmuir 1991, 7, 547;
94. b) R. M. Shroll, D. E. Smith, J. Chem. Phys. 1999, 111, 9025.
95. P. W. Atkins, Physical Chemistry, Oxford University Press, Oxford, 1990, chap. 5.
96. D. R. Stull, E. F. Westrum, Jr., G. C. Sinke, The Chemical Thermodynamics of Organic Compounds, John Wiley and Sons, New York, 1969.
97. 2, respectively.
98. P. J. Domaille, Inorg. Syn. 1990, 27, 96.