An Unusual Polyoxomolybdate: Giant Wheels Linked to Chains

Angewandte Chemie (International Edition in English)

Volumn 36, Issue 5, 1997, Pages 484-486

  Müller, Achim ^a   Krickemeyer, Erich ^a   Bögge, Hartmut ^a   Schmidtmann, Marc ^a   Peters, Frank ^a   Menke, Carsten ^a   Meyer, Jochen ^a  

^a BIELEFELD UNIVERSITY   (Germany)

Author keywords

Clusters; Macrocycles; Molybdenum; Polyoxometalates; Supramolecular chemistry

Indexed keywords

EID: 0030903537     PISSN: 05700833     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.199704841     Document Type: Article

References (33)

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2. a) A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984; H. J. Rösler, Lehrbuch der Mineralogie, 3rd ed., Deutscher Verlag für Grundstoffindustrie, Leipzig, 1984; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34; A. Müller, Nature 1991, 352, 115; From Platonic Solids to Anti-Retroviral Activity, (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. I. Khan, J. Zubieta, frog. Inorg. Chem. 1995, 43, 1-149; A. Müller, C. Beugholt, Nature 1996, 383, 296;
3. a) A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984; H. J. Rösler, Lehrbuch der Mineralogie, 3rd ed., Deutscher Verlag für Grundstoffindustrie, Leipzig, 1984; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34; A. Müller, Nature 1991, 352, 115; From Platonic Solids to Anti-Retroviral Activity, (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. I. Khan, J. Zubieta, frog. Inorg. Chem. 1995, 43, 1-149; A. Müller, C. Beugholt, Nature 1996, 383, 296;
4. a) A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984; H. J. Rösler, Lehrbuch der Mineralogie, 3rd ed., Deutscher Verlag für Grundstoffindustrie, Leipzig, 1984; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34; A. Müller, Nature 1991, 352, 115; From Platonic Solids to Anti-Retroviral Activity, (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. I. Khan, J. Zubieta, frog. Inorg. Chem. 1995, 43, 1-149; A. Müller, C. Beugholt, Nature 1996, 383, 296;
5. a) A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984; H. J. Rösler, Lehrbuch der Mineralogie, 3rd ed., Deutscher Verlag für Grundstoffindustrie, Leipzig, 1984; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34; A. Müller, Nature 1991, 352, 115; From Platonic Solids to Anti-Retroviral Activity, (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. I. Khan, J. Zubieta, frog. Inorg. Chem. 1995, 43, 1-149; A. Müller, C. Beugholt, Nature 1996, 383, 296;
6. a) A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984; H. J. Rösler, Lehrbuch der Mineralogie, 3rd ed., Deutscher Verlag für Grundstoffindustrie, Leipzig, 1984; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34; A. Müller, Nature 1991, 352, 115; From Platonic Solids to Anti-Retroviral Activity, (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. I. Khan, J. Zubieta, frog. Inorg. Chem. 1995, 43, 1-149; A. Müller, C. Beugholt, Nature 1996, 383, 296;
7. a) A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984; H. J. Rösler, Lehrbuch der Mineralogie, 3rd ed., Deutscher Verlag für Grundstoffindustrie, Leipzig, 1984; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34; A. Müller, Nature 1991, 352, 115; From Platonic Solids to Anti-Retroviral Activity, (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. I. Khan, J. Zubieta, frog. Inorg. Chem. 1995, 43, 1-149; A. Müller, C. Beugholt, Nature 1996, 383, 296;
8. a) A. F. Wells, Structural Inorganic Chemistry, 5th ed., Clarendon, Oxford, 1984; H. J. Rösler, Lehrbuch der Mineralogie, 3rd ed., Deutscher Verlag für Grundstoffindustrie, Leipzig, 1984; M. T. Pope, A. Müller, Angew. Chem. 1991, 103, 56; Angew. Chem. Int. Ed. Engl. 1991, 30, 34; A. Müller, Nature 1991, 352, 115; From Platonic Solids to Anti-Retroviral Activity, (Eds.: M. T. Pope, A. Müller), Kluwer, Dordrecht, 1994; M. I. Khan, J. Zubieta, frog. Inorg. Chem. 1995, 43, 1-149; A. Müller, C. Beugholt, Nature 1996, 383, 296;
9. b) A. Müller, H. Reuter, S. Dillinger, Angew. Chem. 1995, 107, 2505; Angew. Chem. Int. Ed. Engl. 1995, 34, 2328.
10. b) A. Müller, H. Reuter, S. Dillinger, Angew. Chem. 1995, 107, 2505; Angew. Chem. Int. Ed. Engl. 1995, 34, 2328.
11. J.-P. Jolivet, M. Henry, J. Livage, De la solution à l'oxyde, Inter- Éditions/ CNRS Éditions, Paris, 1994.
12. a) A. Müller, E. Krickemeyer, J. Meyer, H. Bögge, F. Peters, W. Plass, E. Diemann, S. Dillinger, F. Nonnenbruch, M. Randerath, C. Menke, Angew. Chem, 1995, 107, 2293; Angew. Chem. Int. Ed. Engl. 1995, 34, 2122;
13. a) A. Müller, E. Krickemeyer, J. Meyer, H. Bögge, F. Peters, W. Plass, E. Diemann, S. Dillinger, F. Nonnenbruch, M. Randerath, C. Menke, Angew. Chem, 1995, 107, 2293; Angew. Chem. Int. Ed. Engl. 1995, 34, 2122;
14. b) A. Müller, E. Diemann, B. Hollmann, H. Ratajczak, Naturwissenschaften 1996, 83, 321.
15. A. Müller, J. Meyer, E. Krickemeyer, E. Diemann, Angew. Chem. 1996, 108, 1296; Angew. Chem. Int. Ed. Engl. 1996, 35, 1206.
16. A. Müller, J. Meyer, E. Krickemeyer, E. Diemann, Angew. Chem. 1996, 108, 1296; Angew. Chem. Int. Ed. Engl. 1996, 35, 1206.
17. A. Müller, E. Krickemeyer, S. Dillinger, H. Bögge, W. Plass, A. Proust, L. Dloczik, C. Menke, J. Meyer, R. Rohlfing, Z. Anorg. Allg. Chem. 1994, 620, 599; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, A. Proust, C. Beugholt, U. Bergmann, Angew. Chem. 1994, 106, 897; Angew. Chem. Int. Ed. Engl. 1994, 33, 849; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, C. Beugholt, U. Bergmann, Monatsh. Chem. 1994, 125, 525; A. Müller, H. Bögge, E. Krickemeyer, S. Dillinger, Bull. Pol. Acad. Sci. (Chem.) 1994, 42, 291.
18. A. Müller, E. Krickemeyer, S. Dillinger, H. Bögge, W. Plass, A. Proust, L. Dloczik, C. Menke, J. Meyer, R. Rohlfing, Z. Anorg. Allg. Chem. 1994, 620, 599; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, A. Proust, C. Beugholt, U. Bergmann, Angew. Chem. 1994, 106, 897; Angew. Chem. Int. Ed. Engl. 1994, 33, 849; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, C. Beugholt, U. Bergmann, Monatsh. Chem. 1994, 125, 525; A. Müller, H. Bögge, E. Krickemeyer, S. Dillinger, Bull. Pol. Acad. Sci. (Chem.) 1994, 42, 291.
19. A. Müller, E. Krickemeyer, S. Dillinger, H. Bögge, W. Plass, A. Proust, L. Dloczik, C. Menke, J. Meyer, R. Rohlfing, Z. Anorg. Allg. Chem. 1994, 620, 599; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, A. Proust, C. Beugholt, U. Bergmann, Angew. Chem. 1994, 106, 897; Angew. Chem. Int. Ed. Engl. 1994, 33, 849; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, C. Beugholt, U. Bergmann, Monatsh. Chem. 1994, 125, 525; A. Müller, H. Bögge, E. Krickemeyer, S. Dillinger, Bull. Pol. Acad. Sci. (Chem.) 1994, 42, 291.
20. A. Müller, E. Krickemeyer, S. Dillinger, H. Bögge, W. Plass, A. Proust, L. Dloczik, C. Menke, J. Meyer, R. Rohlfing, Z. Anorg. Allg. Chem. 1994, 620, 599; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, A. Proust, C. Beugholt, U. Bergmann, Angew. Chem. 1994, 106, 897; Angew. Chem. Int. Ed. Engl. 1994, 33, 849; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, C. Beugholt, U. Bergmann, Monatsh. Chem. 1994, 125, 525; A. Müller, H. Bögge, E. Krickemeyer, S. Dillinger, Bull. Pol. Acad. Sci. (Chem.) 1994, 42, 291.
21. A. Müller, E. Krickemeyer, S. Dillinger, H. Bögge, W. Plass, A. Proust, L. Dloczik, C. Menke, J. Meyer, R. Rohlfing, Z. Anorg. Allg. Chem. 1994, 620, 599; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, A. Proust, C. Beugholt, U. Bergmann, Angew. Chem. 1994, 106, 897; Angew. Chem. Int. Ed. Engl. 1994, 33, 849; A. Müller, W. Plass, E. Krickemeyer, S. Dillinger, H. Bögge, A. Armatage, C. Beugholt, U. Bergmann, Monatsh. Chem. 1994, 125, 525; A. Müller, H. Bögge, E. Krickemeyer, S. Dillinger, Bull. Pol. Acad. Sci. (Chem.) 1994, 42, 291.
22. 2O ligand. The sodium atoms are disordered to the extent that it was not possible to determine all of their positions. Therefore, several sodium analyses were carried out. The detection of a somewhat higher Na value than expected from the given formula for 1 correlated with the discovery of chloride in the elemental analysis (about 0.4% Cl corresponding to about 0.4% Na excess). The presence of about 1000 atoms in the asymmetric unit of 1 could indicate that we are dealing here with one of the most complicated inorganic structures. The figures were prepared with the program DIAMOND ("Diamond, Informationssystem für Kristallstrukturen" by Dr. K. Brandenburg, Universität Bonn, Germany). Further details of the crystal structure investigation may be obtained from the Fachinformationszentrum Karlsruhe. D-76344 biggenstein-Leopoldshafen (Germany), on quoting the depository number CSD-406337.
23. 8} groups are involved in the related electron delocalization [8]. The number of delocalized electrons (in the 4d pseudo band) is 33±3, also practically in agreement with the given charge of the anion of 2, at the lower limit of error (20- [3a], which corresponds to the more realistic value).
24. 3 (see A. F. Wells, ref. [1a], pp. 617-618) that demonstrate conductor as well as storage properties of electrons and protons (for general aspects see also Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides, (Ed.: C. Schlenker), Kluwer, Dordrecht, 1989).
25. 3 (see A. F. Wells, ref. [1a], pp. 617-618) that demonstrate conductor as well as storage properties of electrons and protons (for general aspects see also Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides, (Ed.: C. Schlenker), Kluwer, Dordrecht, 1989).
26. 3 (see A. F. Wells, ref. [1a], pp. 617-618) that demonstrate conductor as well as storage properties of electrons and protons (for general aspects see also Low-Dimensional Electronic Properties of Molybdenum Bronzes and Oxides, (Ed.: C. Schlenker), Kluwer, Dordrecht, 1989).
27. See for example: Holleman-Wiberg: Lehrbuch der Anorganischen Chemie, 101 st ed., de Gruyter, Berlin, 1995, pp. 1462-1463.
28. P. Ball, Designing the Molecular World, Princeton University Press, Princeton, 1994, pp. 66-73; Y. Izumi, K. Urabe, M. Onaka, Zeolite, Clay, and Heteropoly Acid in Organic Reactions, VCH, Weinheim, 1992.
29. P. Ball, Designing the Molecular World, Princeton University Press, Princeton, 1994, pp. 66-73; Y. Izumi, K. Urabe, M. Onaka, Zeolite, Clay, and Heteropoly Acid in Organic Reactions, VCH, Weinheim, 1992.
30. S. Mann, G. A. Ozin, Nature 1996, 382, 313.
31. See also Biomimetic Materials Chemistry. (Ed.: S. Mann), VCH, New York, 1996.
32. G. Nicolis, I. Prigogine, Exploring Complexity, Freeman, New York, 1989.
33. Compound 2 shows interesting catalytic behavior as in its presence, novel carbon cages are formed (Sir H. Kroto, private communication).