Removal of Alkanethiols from a Hydrocarbon Mixture by a Heterogeneous Reaction with Metal Oxides

Industrial and Engineering Chemistry Research

Volumn 42, Issue 26, 2003, Pages 6919-6923

  Nehlsen, James P ^a   Benziger, Jay B ^a   Kevrekidis, Ioannis G ^a  

^a Princeton University   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BARIUM COMPOUNDS; EXTRACTION; FILTRATION; LEAD COMPOUNDS; MERCURY COMPOUNDS; ORGANIC SOLVENTS; OXIDES; SULFUR COMPOUNDS; THERMODYNAMICS;

HETEROGENEOUS REACTIONS;

HYDROCARBONS;

HYDROCARBON; METAL OXIDE; THIOL DERIVATIVE;

ALKANE; CHEMICAL REACTION; FILTRATION; HYDROCARBON; METAL OXIDE; SEPARATION;

ARTICLE; CHEMICAL REACTION; FILTRATION; HYDROPHOBICITY; PREDICTION; ROOM TEMPERATURE; THERMODYNAMICS;

EID: 0346276858     PISSN: 08885885     EISSN: None     Source Type: Journal    
DOI: 10.1021/ie030665k     Document Type: Article

References (24)

1. Sharipov, A. K. Mercaptans from Gas Condensate and Crude Oils. Chem. Technol. Fuels Oils 2002, 38 (4), 280-285.
2. Field, L.; Lawson, J. E. Organic Disulfides and Related Substances. I. Oxidation of Thiols to Disulfides with Lead Tetraacetate. J. Am. Chem. Soc. 1958, 80 (4), 838-841.
3. McBryde, W. A. E. Petroleum Deodorized: Early Canadian History of the "Doctor Sweetening" Process. Ann. Sci. 1991, 48, 103-111.
4. Gates, B. C.; Katzer, J. R.; Schuit, G. C. A. Chemistry of Catalytic Processes; McGraw-Hill: New York, 1979.
5. Satterfield, C. N. Heterogeneous Catalysis in Industrial Practice; McGraw-Hill: New York, 1991.
6. Control of Air Pollution from New Motor Vehicles: Tier 2 Motor Vehicle Emissions Standards and Gasoline Sulfur Control Requirements; Federal Register fr10fe00-18; U.S. EPA: Washington, DC, Apr 10, 2000; pp 6697-6870.
7. Naim, M.; Zuker, I.; Zehavi, U.; Rouseff, R. L. Inhibition by Thiol Compounds of Off-Flavor Formation in Stored Orange Juice. 2. Effect of L-Cysteine and N-Acetyl-L-Cysteine on p-Vinylguaiacol Formation. J. Agric. Food Chem. 1993, 41 (9), 1359-1361.
8. Mottram, D. S.; Szauman Szumski, C.; Dodson, A. Interaction of Thiol and Disulfide Flavor Compounds with Food Components. J. Agric. Food Chem. 1996, 44 (8), 2349-2351.
9. Herradura, P. S.; Pendola, K. A.; Guy, R. K. Copper-Mediated Cross-Coupling of Aryl Boronic Acids and Alkyl Thiols. Org. Lett, 2000, 2 (14), 2019-2022.
10. Reid, E. E. Organic Chemistry of Bivalent Sulfur; Chemical Publishing Co.: New York, 1958.
11. Tiers, G. V. D.; Brostrom, M. L. Lead Mercaptides: Materials Useful as Powder Secondary Standards and Internal References for Calibration of X-ray Diffractometers at Small and Medium Angles. J. Appl. Crystallogr. 2000, 33 (3, part 2), 915-920.
12. Borgstrom, P.; Ellis, L. M.; Reid, E. E. Preparation, Properties, and Reactions of Lead Mercaptides. J. Am. Chem. Soc. 1929, 51, 3649-3651.
13. Chen, S. W.; Truax, L. A.; Sommers, J. M. Alkanethiolate-Protected PbS Nanoclusters: Synthesis, Spectroscopic and Electrochemical Studies. Chem. Mater. 2000, 12 (12), 3864-3870.
14. Liu, G.; Rodriguez, J. A.; Dvorak, J.; Hrbek, J.; Jirsak, T. Chemistry of Sulfur-Containing Molecules on Au(111): Thiophene, Sulfur Dioxide, and Methanethiol Adsorption. Surf. Sci. 2002, 505 (1-3), 295-307.
15. Benziger, J. B.; Preston, R. E. Organosulfur Chemistry on W(211) Surfaces. 1. A Comparison of Methanethiol and Methanol. J. Phys. Chem. 1985, 89 (23), 5002-5010.
16. 2(110) Surfaces: A Combined Experimental and Theoretical Study. J. Phys. Chem. B 2002, 106 (38), 9883-9891.
17. Oae, S. Organic Chemistry of Sulfur; Plenum Press: New York, 1977.
18. Oae, S. Organic Sulfur Chemistry: Structure and Mechanism; CRC Press: Boca Raton, FL, 1991.
19. Bensebaa, F.; Zhou, Y.; Deslandes, Y.; Kruus, E.; Ellis, T. H. XPS Studies of Metal-Sulfur Bonds in Metal-Alkanethiolate Materials. Surf. Sci. 1998, 405, L472-476.
20. Souza, A. G. d.; Pinheiro, C. D.; Santos, L. C. R. d.; Melo, M. L. d. M. Standard Enthalpy of Formation of Di-Isobutyldithiocarbamate Complexes of Zinc-Group Elements and Mean M-S Bond-Dissociation Enthalpies. Thermochim. Acta 1994, 231, 31-38.
21. Ribeiro da Silva, M. A. V.; Reis, A. M. M. V.; Ferreira da Silva, M. M. R. Enthalpies of Formation of Crystalline Dimethyldithiocarbamate Complexes of Chromium(III) and Iron(III): The Estimation of the Mean M-S Bond-Dissociation Enthalpies. J. Chem. Thermodyn. 2000, 32, 1319-1325.
22. Ribeiro da Silva, M. A. V.; Reis, A. M. M. V.; Faria, R. I. M. C. P. Standard Enthalpies of Formation of Crystalline Dimethyl Ammoniumdimethyldithiocarbamate and Dimethyldithiocarbamate Complexes of Copper(II) and Nickel(II). The Mean Cu-S and Ni-S Bond-Dissociation Enthalpies. J. Chem. Thermodyn. 1995, 27, 1365-1372.
23. Lide, D. R. CRC Handbook of Chemistry and Physics, 81st ed.; CRC Press: Boca Raton, FL, 2000.
24. Barin, I. Thermochemical Data of Pure Substances; VCH: Weinheim, Germany, 1993; Parts I and II.