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Volumn 344, Issue 6-7, 2002, Pages 657-665

Formal total synthesis of ascidiatrienolide A and the didemnilactones

Author keywords

Medium sized rings; Metathesis; Natural products; Ruthenium; Stereochemistry

Indexed keywords


EID: 0346171216     PISSN: 16154150     EISSN: 15213897     Source Type: Journal    
DOI: 10.1002/1615-4169(200208)344:6/7<657::AID-ADSC657>3.0.CO;2-0     Document Type: Article
Times cited : (45)

References (80)
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    • For a discussion of our strategic goals see: A. Fürstner, Synlett 1999, 1523-1533.
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    • For a short review on the formation of medium rings by RCM, see: M. E. Maier, Angew. Chem. 2000, 112, 2153-2157;
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    • The same reaction in toluene at 80 °C was substantially less efficient (29% yield, E:Z = 6:1)
    • The same reaction in toluene at 80 °C was substantially less efficient (29% yield, E:Z = 6:1).
  • 59
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    • Angew. Chem. Int. Ed. 1999, 38, 2416-2419;
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    • For examples showing that catalyst 13 and congeners can lead to significantly altered E/Z-ratios with a strong preference for the thermodynamically more stable isomer, see the following for leading references: a) C. W. Lee, R. H. Grubbs, Org. Lett. 2000, 2, 2145-2147;
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    • Note that (Z)-configured cycloalkenes with ring sizes ≥ 12 can be selectively prepared by a sequence comprising ring closing alkyne metathesis followed by Lindlar reduction, cf.: a) A. Fürstner, G. Seidel, Angew. Chem. 1998, 110, 1758-1760;
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    • Fürstner, A.1    Seidel, G.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.