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"Face-on" and "edge-on" oriented assemblies have also been observed for other aromatic molecules. See: a) P. Samori, H. Engelkamp, P. de Witte, A. E. Rowan, R. J. M. Nolte, J. P. Rabe, Angew. Chem. Int. Ed. 2001, 40, 2348. b) C. B. France, P. G. Schroeder, B. A. Parkinson, Nano Lett. 2002, 2, 693.
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"Face-on" and "edge-on" oriented assemblies have also been observed for other aromatic molecules. See: a) P. Samori, H. Engelkamp, P. de Witte, A. E. Rowan, R. J. M. Nolte, J. P. Rabe, Angew. Chem. Int. Ed. 2001, 40, 2348. b) C. B. France, P. G. Schroeder, B. A. Parkinson, Nano Lett. 2002, 2, 693.
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0346291263
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note
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It should be noted here that the extremely low tunneling current of 1 pA was essential for observing these structures. At increased current values the resolution became very poor and in some cases the structures disappeared, even when the current was lowered to 1 pA again.
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27
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0001227655
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Experimental data and molecular modeling calculations have shown that π-π interactions between zinc porphyrins are stronger than between free base porphyrins. See: C. A. Hunter, J. K. M. Sanders, J. Am. Chem. Soc. 1990, 112, 5525.
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0346921215
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note
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The herringbone-like fine structure observed by STM is tentatively attributed to the propeller-like structure of the molecule (see Biemans et al. [11]) and is currently under further investigation.
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note
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1H NMR data showed that in solution the BIPY ligands bind to Zn1 orders of magnitude weaker than to DABCO, however, the complicated UV-vis titration curves were inconclusive about the binding stoichiometry.
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