Silylketenes under Kulinkovich conditions: Alkene/ketene exchange versus nucleophilic addition. Application to the stereoselective preparation of vinylcyclopropanols

Tetrahedron Letters

Volumn 44, Issue 51, 2003, Pages 9193-9196

  Raponi, Eric ^a   Pons, Jean Marc ^a  

^a AIX MARSEILLE UNIVERSITY   (France)

Author keywords

Aldehyde; Exchange; Low valent titanium; Silylketene

Indexed keywords

ALDEHYDE; ALKENE; CARBONYL DERIVATIVE; KETENE DERIVATIVE; ORGANOTITANIUM; PROPANOL; TITANIUM DERIVATIVE; UNCLASSIFIED DRUG; VINYL DERIVATIVE; VINYLCYCLOPROPANOL;

ADDITION REACTION; ARTICLE; CHEMICAL REACTION; STEREOCHEMISTRY;

EID: 0345708147     PISSN: 00404039     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tetlet.2003.10.026     Document Type: Article

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24. +: 255; MS/MS (30 eV): 255, 237, 219, 109, 95, 57.
25. 3SiOH and hence can be viewed as a Peterson olefination reaction. However, further studies on these reactions are necessary for a better understanding of their mechanism.
26. +], 291, 221, 165, 151, 123, 109, 95, 81, 71, 57.