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Volumn 167, Issue , 1997, Pages 205-232

Site selectivity in reactions of metal hydride halide complexes with acids

Author keywords

Dihydrogen complex; Halide; Hydride; Protonation

Indexed keywords


EID: 0031321409     PISSN: 00108545     EISSN: None     Source Type: Journal    
DOI: 10.1016/s0010-8545(97)00054-4     Document Type: Article
Times cited : (41)

References (100)
  • 7
    • 0345877637 scopus 로고    scopus 로고
    • note
    • The terms oxidative addition and reductive elimination refer to overall reactions, with no mechanistic implications (i.e. concerted vs stepwise).
  • 11
    • 0004214539 scopus 로고
    • Wiley-Interscience, New York
    • G.A. Olah, Halonium Ions, Wiley-Interscience, New York, 1975.
    • (1975) Halonium Ions
    • Olah, G.A.1
  • 12
    • 85085783382 scopus 로고    scopus 로고
    • note
    • 6 and HOTf are used.
  • 22
    • 0345877634 scopus 로고    scopus 로고
    • note
    • "Stretched" (intermediate length) dihydrogen ligands are arbitrarily defined to have H-H distances of 1.0-1.5 Å.
  • 30
    • 0002703891 scopus 로고
    • and references therein
    • K.G. Caulton, New J. Chem. 18 (1994) 25 and references therein.
    • (1994) New J. Chem. , vol.18 , pp. 25
    • Caulton, K.G.1
  • 57
    • 0000091057 scopus 로고
    • and references therein
    • (a) G.A. Lawrance, Chem. Rev. 86 (1986) 17 and references therein;
    • (1986) Chem. Rev. , vol.86 , pp. 17
    • Lawrance, G.A.1
  • 70
    • 0346508387 scopus 로고    scopus 로고
    • note
    • Actually, two stereoisomers of each product are formed, since the quinoline ligand can be oriented with sulfur either cis or trans to the CO ligand.
  • 75
    • 0001348217 scopus 로고
    • and references therein
    • M. Tilset, J. Am. Chem. Soc. 114 (1992) 2740 and references therein.
    • (1992) J. Am. Chem. Soc. , vol.114 , pp. 2740
    • Tilset, M.1
  • 87
    • 0345877630 scopus 로고    scopus 로고
    • note
    • The calculation uses published bond distances and assumes a planar arrangement of C11, Os and the two N atoms, with the Os-N-N angle of 120°.
  • 97
    • 85085781730 scopus 로고    scopus 로고
    • note
    • 2 atmosphere.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.