Entropy Effect on Physical Displacement of Redox Molecules in a Nafion Film as Studied by Double Potential-Step Chronoabsorptometry

Journal of Physical Chemistry B

Volumn 107, Issue 46, 2003, Pages 12662-12667

  Yagi, Masayuki ^a   Takahashi, Masahiko ^a   Teraguchi, Masahiro ^a   Kaneko, Takashi ^a   Aoki, Toshiki ^a  

^a NIIGATA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL ACTIVATION; COMPLEXATION; DIFFUSION; DISSOCIATION; ENTHALPY; ENTROPY; OXIDATION; RATE CONSTANTS; RUTHENIUM COMPOUNDS; SOLVENTS;

REDOX MOLECULES;

PLASTIC FILMS;

EID: 0344962360     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp036146c     Document Type: Article

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32. 3. This result shows that counterion migration does not influence significantly phenomenological CT under the conditions applied in the present system though it should be involved in the CT.