Temperature-controlled charge transfer mechanism in a polymer film incorporating a redox molecule as studied by potential-step chronocouloabsorptometry

Journal of Physical Chemistry B

Volumn 107, Issue 21, 2003, Pages 4975-4981

  Yagi, Masayuki ^a   Sato, Tsutomu ^a  

^a NIIGATA UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACTIVATION ENERGY; CHARGE TRANSFER; CHEMICAL BONDS; ENTROPY; HIGH TEMPERATURE EFFECTS; MOLECULES; REDOX REACTIONS; TEMPERATURE CONTROL;

CHARGE HOPPING; CHARGE TRANSPORT; POLYMER FILM; POTENTIAL STEP CHRONOCOULOABSORPTOMETRY; REDOX MOLECULE;

PLASTIC FILMS;

EID: 0038580583     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp026859f     Document Type: Article

References (38)

1. Molecular design of electrode surface; Murray, R. W., Ed.; John Wiley and Sons: New York, 1992; Vol. 22.
2. Electroanalytical chemistry; Bard, A. J., Ed.; Marcel Dekker: New York, 1996; Vol. 18.
3. Zen, J.-M.; Kumar, A. S. Acc. Chem. Res. 2001, 34, 772.
4. Yagi, M.; Kinoshita, K.; Kaneko, M. J. Phys. Chem. 1996, 100, 11098.
5. Torres, G. R.; Dupart, E.; Mingotaud, C.; Ravaine, S. J. Phys. Chem. B 2000, 104, 9487.
6. Kaneko, M.; Woehrle, D. Adv. Polym. Sci. 1988, 84, 141.
7. Li, W.; Osora, H.; Otero, L.; Duncan, D. C.; Fox, M. A. J. Phys. Chem. A 1998, 102, 5333.
8. Majda, M.; Faulkner, L. R. J. Electroanal. Chem. 1984, 169, 77.
9. Buttry, D. A.; Anson, F. C. J. Electroanal. Chem. 1981, 130, 333.
10. Blauch, D. N.; Saveant, J. M. J. Am. Chem. Soc. 1992, 114, 3323.
11. Blauch, D. N.; Saveant, J. M. J. Phys. Chem. 1993, 97, 6444.
12. White, H. S.; Leddy, J.; Bard, A. J. J. Am. Chem. Soc. 1982, 104, 4811.
13. Leddy, J.; Bard, A. J. J. Electroanal. Chem. 1985, 189, 203.
14. Oyama, N.; Ohsaka, T.; Kaneko, M.; Sato, K.; Matsuda, H. J. Am. Chem. Soc. 1983, 105, 6003.
15. Martin, C. R.; Rubinstein, I.; Bard, A. J. J. Am. Chem. Soc. 1982, 104, 4817.
16. Anson, F. C.; Saveant, J. M.; Shigehara, K. J. Phys. Chem. 1983, 87, 214.
17. Anson, F. C.; Saveant, J. M.; Shigehara, K. J. Am. Chem. Soc. 1983, 105, 1096.
18. Yagi, M.; Mitsumoto, T.; Kaneko, M. J. Electroanal. Chem. 1997, 437, 219.
19. Yagi, M.; Mitsumoto, T.; Kaneko, M. J. Electroanal. Chem. 1998, 448, 131.
20. Yagi, M.; Yamase, K.; Kaneko, M. J. Electroanal. Chem. 1999, 476, 159.
21. Yagi, M.; Yamase, K.; Kaneko, M. Electrochim. Acta 2002, 47, 2019.
22. Kinoshita, K.; Yagi, M.; Kaneko, M. Electrochim. Acta 1999, 44, 1771.
23. He, P.; Chen, X. J. Electroanal. Chem. 1988, 256, 353.
24. Zhang, J.; Zhao, F.; Abe, T.; Kaneko, M. Electrochim. Acta 1999, 45, 399.
25. Hemingwey, N. E.; Bard, A. J. J. Am. Chem. Soc. 1973, 95, 6582.
26. Crutchley, R. J.; Lever, A. B. P. J. Am. Chem. Soc. 1980, 102, 7128.
27. Kalyanasundaram, K. J. Phys. Chem. 1986, 90, 2285.
28. Rillema, D. P.; Allen, G.; Meyer, T. J.; Conrad, D. Inorg. Chem. 1983, 22, 1617.
29. Crutchley, R. J.; Lever, A. B. P. Inorg. Chem. 1982, 21, 2276.
30. -4 cm.
31. + reduction is sufficiently suppressed at the applied potential (-1.0 V vs SCE) employed in the PSCCA measurements when taking an overpotential into account.
32. CT in the CT analysis for the wide range of its application to electrochemical research.
33. -1 M. In a similar concentration range to that for the present work, we reported that the first-order rate constant for physical displacement of a redox molecule in a Nafion film is independent of its concentration.
34. c reflect the CT dynamics arising from the nature and reactions of the complexes.
35. s are the complex concentrations in the film and aqueous solution at an equilibrium state.
36. Yagi, M.; Nagai, K.; Onikubo, T.; Kaneko, M. J. Electroanal. Chem. 1995, 383, 61.
37. Yagi, M.; Nagai, K.; Kira, A.; Kaneko, M. J. Electroanal. Chem. 1995, 394, 169.
38. +.