Reaction of (μ-oxo)diiron(III) core with Co2 in N-methylimidazole: Formation of mono(μ-carboxylato)(μ-oxo)diiron(III) complexes with N-methylimidazole as ligands

Inorganic Chemistry

Volumn 42, Issue 5, 2003, Pages 1681-1687

  Marlin, Dana S ^a   Olmstead, Marilyn M ^b   Mascharak, Pradip K ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

1 METHYLIMIDAZOLE; CARBON DIOXIDE; DIIRON DERIVATIVE; IRON COMPLEX; LIGAND; UNCLASSIFIED DRUG; WATER;

ADDITION REACTION; ARTICLE; CHEMICAL STRUCTURE; REACTION ANALYSIS; STOICHIOMETRY; SYNTHESIS;

CARBON DIOXIDE; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; IRON COMPOUNDS; LIGANDS; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; ORGANOMETALLIC COMPOUNDS; OXIDATION-REDUCTION;

EID: 0344519571     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0206140     Document Type: Article

References (45)

1. Feig, A. L.; Lippard, S. J. Chem. Rev. 1994, 94, 759.
2. Du Bois, J.; Mizoguchi, T. J.; Lippard, S. J. Coord. Chem. Rev. 2000, 200-202, 443.
3. Kurtz, D. M., Jr. Chem. Rev. 1990, 90, 585.
4. Marlin, D. S.; Mascharak, P. K. In Encyclopedia of Catalysis: Biomimetic Catalysis by Models of Non-Heme Iron Enzymes; Horváth, I. T., Ed.; John Wiley & Sons: New York, in press.
5. Solomon, E. I.; Brunold, T. C.; Davis, M. I.; Kemsley, J. N.; Lee, S.-K.; Lehnert, N.; Neese, F.; Skulan, A. J.; Yang, Y.-S.; Zhou, J. Chem. Rev. 2000, 100, 235.
6. Wallar, B. J.; Lipscomb, J. D. Chem. Rev. 1996, 96, 2625.
7. Que, L. Jr.; True, A. E. In Progress in Inorganic Chemistry Bioinorganic Chemistry; Lippard, S. J., Ed.; John Wiley & Sons: New York, 1990; Vol. 38, p 97.
8. Lippard, S. J. Angew. Chem., Int. Ed. Engl. 1988, 27, 344.
9. Ookubo, T.; Sugimoto, H.; Nagayama, T.; Masuda, H.; Sato, T.; Tanaka, K.; Maeda, Y.; Okawa, H.; Hayashi, Y.; Uehara, A.; Suzuki, M. J. Am. Chem. Soc. 1996, 118, 701.
10. Dong, Y.; Yan, S. Young, V. G., Jr.; Que, L., Jr. Angew. Chem., Int. Ed. Engl. 1996, 35, 618.
11. Oh, S. M.; Hendrickson, D. N.; Hassett, K. L.; Davis, R. E. J. Am. Chem. Soc. 1985, 107, 8009.
12. Wu, F.-J.; Kurtz, D. M., Jr. J. Am. Chem. Soc. 1989, 111, 6563.
13. Hodgkinson, J.; Jordan, R. B. J. Am. Chem. Soc. 1973, 95, 763.
14. Miller, L. L.; Jacobson, R. A.; Chen, Y.-S.; Kurtz, D. M., Jr. Acta Crystallogr. 1989, C45, 527.
15. Cotton, F. A.; Wilkinson, G. Advanced Inorganic chemistry, 5th ed.; Wiley-Interscience: New York, 1988; p 718.
16. Christie, S.; Subramanian, S.; Wang, L.; Zaworotko, M. J. Inorg. Chem. 1993, 32, 5415.
17. 18
18. Bond, A. M.; Clark, R. J. H.; Humphrey, D. G.; Panayiotopoulos, P.; Skelton, B. W.; White, A. H. J. Chem. Soc., Dalton Trans. 1998, 11, 1845.
19. In the syntheses of 4 and 5, a small amount of 2 was also isolated from the reaction mixture. The almost colorless crystals accumulate near the junction of the two solutions. These crystals can be physically separated from the desired product without much trouble.
20. Dorfman, J. R.; Girerd, J.-J.; Simhon, E. D.; Stack, T. D. P.; Holm, R. H. Inorg. Chem. 1984, 23, 4407 and references therein.
21. Yan, S.; Que, L., Jr.; Taylor, L. F.; Anderson, O. P. J. Am. Chem. Soc. 1988, 110, 5222.
22. Yan, S.; Cox, D. D.; Pearce, L. L.; Juarez-Garcia, C.; Que, L., Jr.; Zhang, J. H.; O'Connor, C. J. Inorg. Chem. 1989, 28, 2509.
23. Norman, R. E.; Yan, S.; Que, L., Jr.; Backes, G.; Ling, J.; Sanders-Loehr, J.; Zhang, J. H.; O'Connor, C. J. J. Am. Chem. Soc. 1990, 112, 1554.
24. Norman, R. E.; Leising, R. A.; Yan, S.; Que, L., Jr. Inorg. Chim. Acta 1998, 273, 393.
25. Lee, D.; Lippard, S. J. Inorg. Chem. 2002, 41, 827 and references therein.
26. Armstrong, W. H.; Spool, A.; Papaefthymiou, G. C.; Frankel, R. B.; Lippard, S. J. J. Am. Chem. Soc. 1984, 106, 3653.
27. Hartman, J. A. R.; Rardin, R. L.; Chaudhuri, P.; Pohl, K.; Wieghardt, K.; Nuber, B.; Weiss, J.; Papaefthymiou, G. C.; Frankel, R. B.; Lippard, S. J. J. Am. Chem. Soc. 1987, 109, 7387.
28. Vincent, J. B.; Huffman, J. C.; Christou, G.; Li, Q.; Nanny, M. A.; Hendrickson, D. N.; Fong, R. H.; Fish, R. H. J. Am. Chem. Soc. 1988, 110, 6898.
29. Palmer, D. A.; Van Eldik, R. Chem. Rev. 1983, 83, 651.
30. Drüeke, S.; Wieghardt, K.; Nuber, B.; Weiss, J. Inorg. Chem. 1989, 28, 1414.
31. Norman, R. E.; Holz, R. C.; Ménage, S.; O'Connor, C. J.; Zhang, J. H.; Que, L., Jr. Inorg. Chem. 1990, 29, 4629.
32. Fujita, T.; Ohba, S.; Nishida, Y.; Goto, A.; Tokii, T. Acta Crystallogr. 1994, C50, 544.
33. Arulsamy, N.; Goodson, P. A.; Hodgson, D. J.; Glerup, J.; Michelsen, K. Inorg. Chim. Acta 1994, 216, 21.
34. Hazell, R.; Jensen, K. B.; McKenzie, C. J.; Toftlund, H. J. Chem. Soc., Dalton Trans. 1995, 707.
35. For example, see: Darensbourg, D. J.; Frost, B. J.; Larkins, D. L. Inorg. Chem. 2001, 40, 1993.
36. Chisholm, M. H.; Extine, M. W. J. Am. Chem. Soc. 1977, 99, 782, 792.
37. We have reported similar spontaneous reduction of Fe(III) complexes of polypyridine ligands in acetonitrile solvent. See: Patra, A. K.; Olmstead, M. M.; Mascharak, P. K. Inorg. Chem. 2002, 41, 5403.
38. Chum, H. L.; Koran, D.; Osteryoung, R. A. J. Am. Chem. Soc. 1978, 100, 310.
39. Maturano, M. D.; Bongibault, V.; Willson, M.; Klaébé, A.; Fournier, D. Tetrahedron 1997, 53, 17241.
40. Wedemeyer-Exl, C.; Darbre, T.; Keese, R. Helv. Chim. Acta 1999, 82, 1173.
41. Kersting, B. Angew. Chem., Int. Ed. 2001, 40, 3988.
42. Presence of N-methyl imidazolium ion in the reaction mixture (Scheme 2) possibly makes the transfer of methyl group more facile at this step.
43. 2 to afford the methyl carbonato complex 5. In absence of detailed studies, this remains as another viable mechanism at this time.
44. Kato, M.; Ito, T. Inorg. Chem. 1985, 24, 509.
45. Pavlishchuk, V.; Birkelbach, F.; Weyhermuller, T.; Wieghardt, K.; Chaudhuri, P. Inorg. Chem. 2002, 41, 4405.