One-Pot Three-Component Tandem Metathesis/Diels-Alder Reaction

Organic Letters

Volumn 5, Issue 19, 2003, Pages 3439-3442

  Lee, Hee Yoon ^a   Kim, Hyoun Young ^a   Tae, Hyunsup ^a   Kim, Byung Gyu ^a   Lee, Jaeyoung ^a  

^a Korea Advanced Institute of Science and Technology (KAIST)   (South Korea)

Author keywords

[No Author keywords available]

Indexed keywords

ARTICLE; CHEMICAL REACTION; DIELS ALDER REACTION; RING CLOSING METATHESIS; STEREOCHEMISTRY; STEREOISOMERISM;

EID: 0344309090     PISSN: 15237060     EISSN: None     Source Type: Journal    
DOI: 10.1021/ol035194c     Document Type: Article

References (39)

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32. 2 (0.01 M) was stirred at room temperature for 1.0 h, and the solvent was evaporated. Then, the residue was purified by flash column chromatography on silica gel to afford the desired diene product.
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37. 2 (0.05 M) under an Argon atmosphere. Grubbs second-generation catalyst (10 mol %) was added to the reaction mixture at room temperature, and the resulting mixture was heated to reflux for 3-5 h. After the mixture was cooled to room temperature, the solvent was removed under reduced pressure. Then, the residue was purified by flash column chromatography on silica gel to afford the desired diene product.
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39. 2 was added to the reaction mixture. After the mixture was refluxed for 3-5 days, the reaction mixture was cooled to room temperature and concentrated under reduced pressure. Then, the residue was purified by flash column chromatography on silica gel to afford the desired product.