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Volumn 22, Issue 24, 2003, Pages 5092-5099

New Reactivity Modes of Chromium(0) Fischer Carbene Complexes: Unprecedented Insertion of a Carbene Ligand into an Active B-H Bond

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL STRUCTURE; DIMERIZATION; ELECTRONIC PROPERTIES; HYDRIDES; HYDROGEN BONDS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; OXIDATION; QUENCHING; REDUCTION; X RAY DIFFRACTION ANALYSIS;

EID: 0344012470     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om034010v     Document Type: Article
Times cited : (18)

References (77)
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    • Selected reviews on the chemistry of metal carbene (Fischer) complexes; (a) Dötz, K. H.; Fischer, H.; Hofmann, P.; Kreissel, F. R.; Schubert, U.; Weiss, K. Transition Metal Carbene Complexes; Verlag Chemie: Deerfield Beach, FL, 1983. (b) Dötz, K. H. Angew. Chem., Int. Ed. Engl. 1984, 23, 587. (c) Wulff, W. D. In Comprehensive Organic Synthesis; Trost, B. M., Fleming, I., Eds.; Pergamon: Oxford, U.K., 1991; Vol. 5, p 1065. (d) Hegedus, L. S. In Comprehensive Organometallic Chemistry II; Abel, E. W., Stone, F. G. A., Wilkinson, G., Eds.; Pergamon: Oxford, U.K., 1995; Vol. 12, p 549. (e) Harvey, D. F. Sigano, D. M. Chem. Rev. 1996, 96, 271. (f) Barluenga, J.; Fañanás, F. J. Tetrahedron 2000, 56, 4597. (g) Sierra, M. A. Chem. Rev. 2000, 100, 3591.
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    • Barluenga, J.1    Fañanás, F.J.2
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    • Reviews on the chemistry of α,β-unsaturated group 6 carbene complexes: (a) Barluenga, J.; Flórez, J.; Fañanás, F. J. J. Organomet. Chem. 2001, 624, 5. (b) de Meijere, A.; Schirmer, H.; Duetsch, M. Angew. Chem., Int. Ed. 2000, 39, 3964. (c) Aumann, R.; Nienaber, H. Adv. Organomet. Chem. 1997, 41, 163.
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    • Reviews on the chemistry of α,β-unsaturated group 6 carbene complexes: (a) Barluenga, J.; Flórez, J.; Fañanás, F. J. J. Organomet. Chem. 2001, 624, 5. (b) de Meijere, A.; Schirmer, H.; Duetsch, M. Angew. Chem., Int. Ed. 2000, 39, 3964. (c) Aumann, R.; Nienaber, H. Adv. Organomet. Chem. 1997, 41, 163.
    • (2000) Angew. Chem., Int. Ed. , vol.39 , pp. 3964
    • De Meijere, A.1    Schirmer, H.2    Duetsch, M.3
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    • 0001214419 scopus 로고    scopus 로고
    • Reviews on the chemistry of α,β-unsaturated group 6 carbene complexes: (a) Barluenga, J.; Flórez, J.; Fañanás, F. J. J. Organomet. Chem. 2001, 624, 5. (b) de Meijere, A.; Schirmer, H.; Duetsch, M. Angew. Chem., Int. Ed. 2000, 39, 3964. (c) Aumann, R.; Nienaber, H. Adv. Organomet. Chem. 1997, 41, 163.
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    • note
    • 0.5. CCDC 209053 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving-.html (or from the CCDC, 12 Union Road, Cambridge CB2 1EZ, U.K.; fax +44 1223 336033; e-mail deposit*ccdc.cam.ac.uk).
  • 51
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    • β-H bond in boroxycarbene has been reported: (a) Barluenga, J.; Rodríguez, F.; Vadecard, J.; Bendix, M.; Fañanás, F. J.; López-Ortiz, F. J. Am. Chem. Soc. 1996, 118, 6090. (b) Barluenga, J.; Rodríguez, F.; Vadecard, J.; Bendix, M.; Fañanás, F. J.; López-Ortiz, F.; Rodríguez, M. A. J. Am. Chem. Soc. 1999, 121, 8776. See also: (c) Barluenga, J.; Fañanás, F. J. Tetrahedron 2000, 56, 4597.
    • (1996) J. Am. Chem. Soc. , vol.118 , pp. 6090
    • Barluenga, J.1    Rodríguez, F.2    Vadecard, J.3    Bendix, M.4    Fañanás, F.J.5    López-Ortiz, F.6
  • 53
    • 0343932676 scopus 로고    scopus 로고
    • β-H bond in boroxycarbene has been reported: (a) Barluenga, J.; Rodríguez, F.; Vadecard, J.; Bendix, M.; Fañanás, F. J.; López-Ortiz, F. J. Am. Chem. Soc. 1996, 118, 6090. (b) Barluenga, J.; Rodríguez, F.; Vadecard, J.; Bendix, M.; Fañanás, F. J.; López-Ortiz, F.; Rodríguez, M. A. J. Am. Chem. Soc. 1999, 121, 8776. See also: (c) Barluenga, J.; Fañanás, F. J. Tetrahedron 2000, 56, 4597.
    • (2000) Tetrahedron , vol.56 , pp. 4597
    • Barluenga, J.1    Fañanás, F.J.2
  • 58
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    • The spontaneous dimerization of nonstabilized group 6 Fischer carbene complexes has been reported; see: (a) Casey, C. P.; Burkhardt, T. J.; Bunnell, C. A.; Calabrese, J. C. J. Am. Chem. Soc. 1977, 99, 2127. (b) Fischer, H.; Zeuner, S.; Ackermann, K. J. Chem. Soc., Chem. Commun. 1984, 684.
    • (1977) J. Am. Chem. Soc. , vol.99 , pp. 2127
    • Casey, C.P.1    Burkhardt, T.J.2    Bunnell, C.A.3    Calabrese, J.C.4
  • 59
    • 37049111912 scopus 로고
    • The spontaneous dimerization of nonstabilized group 6 Fischer carbene complexes has been reported; see: (a) Casey, C. P.; Burkhardt, T. J.; Bunnell, C. A.; Calabrese, J. C. J. Am. Chem. Soc. 1977, 99, 2127. (b) Fischer, H.; Zeuner, S.; Ackermann, K. J. Chem. Soc., Chem. Commun. 1984, 684.
    • (1984) J. Chem. Soc., Chem. Commun. , pp. 684
    • Fischer, H.1    Zeuner, S.2    Ackermann, K.3
  • 60
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    • Barton, D., Ollis, W. D., Eds.; Pergamon: Oxford, U.K.
    • Pelter, A.; Smith, K. In Comprehensive Organic Chemistry; Barton, D., Ollis, W. D., Eds.; Pergamon: Oxford, U.K., 1979; Vol. 3, p 781.
    • (1979) Comprehensive Organic Chemistry , vol.3 , pp. 781
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  • 71
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    • Complex 6 was prepared by following the method reported by Fischer for the aminolysis of alkoxychromium(0) carbene complexes: Klabunde, U.; Fischer, E. O. J. Am. Chem. Soc. 1967, 89, 7141.
    • (1967) J. Am. Chem. Soc. , vol.89 , pp. 7141
    • Klabunde, U.1    Fischer, E.O.2


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