Application of O2-DMSO as reoxidant in the Pd(II)-catalyzed 1,4-oxidation of 5-substituted 1,3-cyclohexadienes

Acta Chemica Scandinavica

Volumn 51, Issue 6-7, 1997, Pages 773-777

  Rönn, Magnus ^a   Andersson, Pher G ^a   Bäckvall, Jan E ^a  

^a UPPSALA UNIVERSITY   (Sweden)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0342738570     PISSN: 0904213X     EISSN: None     Source Type: Journal    
DOI: 10.3891/acta.chem.scand.51-0773     Document Type: Article

References (33)

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24. When a carbon nucleophile was used in place of an oxygen nucleophile, the diene corresponding to 9 was isolated. In this case the diene is more stable due to the lower leaving-group ability of the carbon: Rönn, M. Unpublished results.
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26. For nucleophilic attack on (π-allyl) palladium complexes in DMSO see Tsuji, J., Takahashi, H. and Morikawa, N. Tetrahedron Lett. (1965) 4387. For nucleophilic attack on (π-allyl)palladium complexes with 1,4-benzoquinone as ligand see Bäckvall, J. E., Nordberg, R. E. and Wilhelm, D. J. Am. Chem. Soc. 107 (1985) 6892; Bäckvall, J. E. and Gogoll, A. Tetrahedron Lett. 29 (1988) 2243.
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