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note
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6 (364.27): calcd. C 56.05; H 3.32; found C 55.89; H 3.25. General Procedure for the Photochemical Benzannulation of Carbene Complex 2: A solution of 1 mmol of carbene complex and 5 mmol of alkyne in 60 ml of tetrahydrofuran was irradiated for 30 min at -20 °C using a mercury vapor lamp (Phillips 125 HPK) and quartz glassware. A color change from purple to brownish yellow occurred. After evaporation of the solvent the residue was chromatographed on silica gel using petroleum ether/diethyl ether mixtures as eluent to give the pure 2,3-dihydro-6-benzopyranols as yellow oils.
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3 complexes, see: Morris, M. J. in Comprehensive Organometallic Chemistry II (Eds.: Abel, E. W.; Stone, F. G. A.; Wilkinson, G.), Pergamon Press, Oxford, 1995, vol. 5, p. 506-509.
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