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14
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85041874263
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note
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β-Cleavage (formation of the aryl radical and the alkyl sulfinate) has also been reported for aryl alkyl suphone when the aromatic ring is substituted by an electron-withdrawing group. (see ref. 10).
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more..
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28
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85041875596
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note
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(a) Hybrid density functional methods with the 6-31G* base have been used previously for calculations on neutral and radical cation of heterocycles containing sulfur atoms and on extended TTF and found to give a good qualitative description of properties. See for example refs. 20b,c and 21c;
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29
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18044401941
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(b) V. Hernández, H. Muguruma, S. Hotta, J. Casado and J. T. López Navarrete, J. Phys. Chem. A, 2000, 104, 735;
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0000156048
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(c) T. Keszthelyi, M. M. -L Grage, J. F. Offersgaard, R. Wilbrandt, C. Svendsen, O. S. Mortensen, J. K. Pedersen and H. J. A Jensen, J. Phys. Chem. A, 2000, 104, 2808.
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0000821227
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Andrieux, C.P.1
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33
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85041870607
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note
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From reversible or quasi-reversible voltammograms, peak-potential separations between the cathodic and anodic processes give a measurement of the kinetics parameters for the heterogeneous electron transfer.
-
-
-
-
34
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-
85041883057
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note
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By comparison with the reversible one-electron oxidation wave of ferrocene.
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-
-
-
35
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85041881432
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note
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-1.
-
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36
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0005972480
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C. P. Andrieux, L. Nadjo and J.-M. Savéant, J. Electroanal. Chem., 1973, 42, 223.
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85041884263
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note
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-1.
-
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-
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38
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-
85041871788
-
-
note
-
-1 concentration of 3b.
-
-
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39
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0000796091
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(a) C. P. Andrieux, A. Le Gorande and J.-M. Savéant, J. Am. Chem. Soc., 1992, 112, 6892;
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0030774162
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(c) C. P. Andrieux, C. Combellas, F. Kanoufi, J.-M. Savéant and A. Thiébault, J. Am. Chem. Soc., 1997, 119, 9540;
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42
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0000450539
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(d) J.-M. Savéant, in Advances in Physical Organic Chemistry, ed. T. T. Tidwell, Academic Press, New York, 2000, vol. 35, p. 177-192 and references therein.
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Savéant, J.-M.1
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43
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85041877748
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note
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According to a development of the dissociative ET model to the decomposition of radical anion, the standard activation energy depends directly on the bond dissociation energy (ΔG°‡ proportional to D/4) (ref. 14).
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