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note
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The validity of this latter point was experimentally ascertained by observing that, as described in the text, a plateau shaped catalytic signal was always obtained. Moreover, increasing the oxygen concentration by saturating the solution with oxygen instead of ambient air yielded only a small increase of catalysis.
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41
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note
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The DigiSim simulation package was also used to simulate the voltammograms in the most general cases. Although this program requires entering a large number of parameters, the exact values of which being often unknown, it allowed us to validate some of the simplifying assumptions used in this work.
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42
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note
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The experimentally observed saturation of the catalytic current with increasing light intensity shows that, under saturating conditions, the charge separation step does not participate in the kinetic control of the catalytic cycle. Within the framework of the kinetic model proposed here, this translates into p being negligible.
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43
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note
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2+: no catalysis was observed in this case.
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