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0001603133
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M while giving an approximately correct diffusion coefficient.
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85087251766
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-1 is obtained by analyzing the shape and position of the nonturnover peaks at increasing scan rates or by using potential step voltammetry.
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85087252632
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note
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•+] form occurs before reduction to the resting enzyme.
-
-
-
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49
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0030906534
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3+ initially generates an Fe(III) π-cation porphyrin radical intermediate, followed by a rate-limiting conversion to the Fe(IV) form of compound II and fast further oxidation to produce compound I (Berglund, J.; Pascher, T.; Winkler, J. R.; Gray, H. B. J. Am. Chem. Soc. 1997, 119, 2464).
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