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Volumn 41, Issue 21, 2003, Pages 3227-3242

Design and Synthesis of Highly Photopolymerizable Styrenyl Compounds in Solid-State Photoinitiated Polymerization

Author keywords

FT IR; Photopolymerization; Styrene derivatives; Thiadiazole; Trichloromethyl triazine

Indexed keywords

DERIVATIVES; GLASS TRANSITION; INITIATORS (CHEMICAL); MONOMERS; STYRENE; SYNTHESIS (CHEMICAL); THERMAL EFFECTS;

EID: 0142200480     PISSN: 0887624X     EISSN: None     Source Type: Journal    
DOI: 10.1002/pola.10915     Document Type: Article
Times cited : (2)

References (30)
  • 9
    • 0142228507 scopus 로고    scopus 로고
    • Mitsubishi Paper Mills Ltd. 2000, unpublished results
    • Furukawa, A. Mitsubishi Paper Mills Ltd. 2000, unpublished results.
    • Furukawa, A.1
  • 22
    • 0142228505 scopus 로고    scopus 로고
    • note
    • The polarizability and dipole moment are calculated as follows. All possible conformations are energy-minimized at the PM3 level with WinMOPAC (version 2.0, Fujitsu, Ltd.), with the criterion for the maximum gradient (GNORM) less than 0.05. The resulting structures are sorted by the energy of formation. For a C1TD molecule, the calculations converge to all possible conformations, and the energy of formation in its most stable conformations, C-1 and C-3 in Figure 4(a), is lower than that in the C-2 conformation by 0.7 kcal/mol in vacua. This result suggests that at room temperature, a C1TD molecule could be in rapid equilibrium between these conformations, as illustrated in Figure 4(a). The values of the calculated polarizabilities and dipole moments are not sensitive to these conformation changes.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.