Synthesis, structure and reactivity of new late transition metal complexes bearing diphosphane ligands derived from bis(pyrazol-1-yl)methane

European Journal of Inorganic Chemistry

Volumn , Issue 17, 2003, Pages 3233-3241

  Otero, Antonio ^a   Carrillo Hermosilla, Fernando ^a   Terreros, Pilar ^b   Expósito, Teresa ^a   Rojas, Sergio ^b   Fernández Baeza, Juan ^a   Antiñolo, Antonio ^a   López Solera, Isabel ^a  

^a UNIVERSITY OF CASTILLA LA MANCHA   (Spain)

^b INSTITUTO DE CATÁLISIS Y PETROLEOQUÍMICA   (Spain)

Author keywords

Hydrogenation; Iridium; Nitrogen heterocycles; Palladium; Phosphanes; Platinum; Rhodium

Indexed keywords

CHELATION; HYDROGENATION; IRIDIUM; LIGANDS; METAL COMPLEXES; METHANE; NITROGEN; PALLADIUM COMPOUNDS; PLATINUM; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL);

BIDENTATE CHELATES; CATALYTIC HYDROGENATION; DIPHOSPHANE; DIPHOSPHANE LIGANDS; HYDROGENATION OF OLEFINS; LATE TRANSITION METALS COMPLEXES; MULTISTEPS; NITROGEN HETEROCYCLES; PHOSPHANES; SULFIDATION;

PALLADIUM;

BIS(PYRAZOL 1 YL)METHANE; DIPHOSPHANE; METAL COMPLEX; METHANE; PHOSPHINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL MODIFICATION; COMPLEX FORMATION; CRYSTAL STRUCTURE; DERIVATIZATION; HYDROGEN BOND; HYDROGENATION; LIGAND BINDING; MOLECULAR DYNAMICS; PHASE TRANSITION; PROTON NUCLEAR MAGNETIC RESONANCE; STRUCTURE ANALYSIS;

EID: 0141703612     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300202     Document Type: Article

References (44)

1. [1a] F. A. Cotton, B. Hong, Prog. Inorg. Chem. 1992, 40, 179.
2. [1b] H. A. Mayer, W. C. Kaska, Chem. Rev. 1994, 94, 1239.
3. [1c] C. Bianchini, A. Meli, M. Peruzzini, F. Vizza, F. Zanobini, Coord. Chem. Rev. 1992, 120, 193.
4. [1d] W. Levason, The Chemistry of Organophosphorus Compounds (Eds.: F. R. Hartley and S. Patai), Wiley, NY, 1990.
5. [2a] M. Álvarez, N. Lugan, R. Mathieu, J. Chem. Soc., Dalton Trans. 1994, 2755.
6. [2b] A. M. Trzeciak, T. Glowiak, J. J. Ziolkowski, J. Organomet. Chem. 1998, 552, 159.
7. [2c] M. Valentini, K. Selvakumer, M. Worle, P. S. Pregosin, J. Organomet. Chem. 1999, 587, 244.
8. [2d] J. D. Kostas, C. G. Screttas, J. Organomet. Chem. 1999, 585, 1.
9. [2e] P. Pelagatti, A. Gacchi, M. Carcelli, M. Costa, A. Fochi, P. Ghidini, E. Leporati, M. Masi, C. Pelizzi, G. Pelizzi, J. Organomet. Chem. 1999, 583, 94.
10. [2f] D. G. Grotjahn, D. Combs, S. Van, G. Aguirre, F. Ortega, Inorg. Chem. 2000, 39, 2080.
11. [2g] G. Esquius, J. Pons, R. Yáñez, J. Ros, J. Organomet. Chem. 2001, 619, 14.
12. [2h] P. Braunstein, M. D. Fryzuk, M. Le Dall, F. Naud, S. J. Rettig, F. Speiser, J. Chem. Soc., Dalton Trans. 2000, 1067.
13. [2i] M. L. Clarke, A. M. Z. Slawin, M. V. Wheatley, J. D. Woolins, J. Chem. Soc., Dalton Trans. 2001, 3421.
14. [2j] J. A. Casares, P. Espinet, J. M. Martín-Álvarez, G. Espino, M. Pérez-Manrique, F. Vattier, Eur. J. Inorg. Chem. 2001, 289.
15. [2k] J. T. Mague, J. L. Krinsky, Inorg. Chem. 2001, 40, 1962.
16. [2l] V. Cadierno, P. Crochet, J. García-Álvarez, S. E. García-Garrido, J. Gimeno, J. Organomet. Chem. 2002, 663, 32.
17. [2m] G. Esquius, J. Pons, R. Yáñez, J. Ros, R. Mathieu, B. Donnadieu, N. Lugan, Eur. J. Inorg. Chem. 2002, 2999.
18. [2n] J. García-Antón, J. Pons, X. Solans, M. Font-Bardia, J. Ros, Eur. J. Inorg. Chem. 2002, 3319.
19. A. Antiñolo, F. Carrillo-Hermosilla, E. Diez-Barra, J. Fernández-Baeza, M. Fernández-López, A. Lara-Sánchez, A. Moreno, A. Otero, A. M. Rodríguez, J. Tejeda, J. Chem. Soc., Dalton Trans. 1998, 3737.
20. [4a] T. S. Lobana, Prog. Inorg. Chem. 1989, 37, 495.
21. [4b] J. R. Dilworth, N. Wheatley, Coord. Chem. Rev. 2000, 199, 89.
22. [4c] P. Das, D. Konwar, P. Sengupta, D. K. Dutta, Transition Met. Chem. 2000, 25, 426.
23. A. R. Katritzky, A. E. Abdel-Rahman, D. E. Leahy, Tetrahedron 1983, 39, 4133.
24. [6a] R. Noyori, Asymmetric Catalysis in Organic Synthesis, John Wiley and Sons, NY, 1994.
25. [6b] H. Takaya, T. Olita, R. Noyori, Catalytic Asymmetric Synthesis, VCH, NY, 1993.
26. [6c] J. M. J. Williams, Catalysis in Asymmetric Synthesis, Sheffield Academic Press, Sheffield, 1999.
27. [7a] D. E. Berry, J. Browning, K. R. Dixon, R. W. Hilts, Can. J. Chem. 1988, 66, 1272.
28. [7b] S. Browing, K. R. Dixon, R. W. Hilts, Organometallics 1989, 8, 552.
29. [7c] J. Browning, K. R. Dixon, R. W. Hilts, N. J. Meanwell, F. Wang, J. Organomet. Chem. 1991, 410, 389.
30. [7d] M. S. Abbassioun, P. A. Chaloner, C. Claver, P. B. Hitchcock, A. M. Masdeu, A. Ruiz, T. Saballs, J. Organomet. Chem. 1991, 403, 229.
31. [7e] C. Claver, F. Gii, J. Viñas, A. Ruiz, Polyhedron 1987, 1329.
32. [7f] C. Claver, A. Ruiz, A. M. Masdeu, J. Viñas, T. Saballs, F. J. Lahoz, F. J. Plou, J. Organomet. Chem. 1989, 373, 269.
33. [8a] P. Nicpon, D. W. Meek, Inorg. Chem. 1967, 6, 145.
34. [8b] E. W. Ainscough, A. H. Brodie, A. R. Furness, J. Chem. Soc., Dalton Trans. 1973, 2360.
35. [9a] S. Trofimenko, J. Am. Chem. Soc. 1970, 92, 5118.
36. [9b] G. Minghetti, M. A. Cinellu, A. K. Bandini, G, Banditelli, F. Demartin, M. Manassero, J. Organomet. Chem. 1986, 315, 387.
37. [9c] P. K. Byers, A. J. Canty, Organometallics 1990, 9, 210.
38. [9d] P. K. Byers, A. J. Canty; R. T. Honeyman, Adv. Organomet. Chem. 1992, 34, 1. [9e] S. Tsuji, D. C. Swenson, R. F. Jordan, Organometallics 1999, 18, 4758.
39. [9e] P. K. Byers, A. J. Canty; R. T. Honeyman, Adv. Organomet. Chem. 1992, 34, 1. [9e] S. Tsuji, D. C. Swenson, R. F. Jordan, Organometallics 1999, 18, 4758.
40. C. H. Bartholomew, P. K. Agrawal, J. R. Katzer, Adv. Catal. 1982, 31, 135.
41. J. Tsuji, Organic Synthesis with Palladium Compounds, Springer, Berlin, 1980, vol. 10, pp. 2-3.
42. E. Diez-Barra, A. de la Hoz, A. Sánchez-Migallón, J. Tejeda, Heterocycles 1992, 34, 1365.
43. G. M. Sheldrick, Acta Crystallogr., Sect. A 1990, 46, 467.
44. G. M. Sheldrick, Program for the Refinement of Crystal Structures from Diffraction Data, University of Göttingen, Göttingen, Germany, 1997.