Mesostructured MTES-derived silica thin film with spherical voids investigated by TEM: 1. Mesostructure determination

Langmuir

Volumn 19, Issue 18, 2003, Pages 7282-7288

  Yu, K ^a   Wu, X ^a   Brinker, C J ^b,c   Ripmeester, J ^a  

^a NATIONAL RESEARCH COUNCIL CANADA   (Canada)

^b SANDIA NATIONAL LABORATORIES   (United States)

^c UNIVERSITY OF NEW MEXICO   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CRYSTAL MICROSTRUCTURE; DIFFRACTION; EVAPORATION; HYDROPHOBICITY; PERMITTIVITY; POLYETHYLENE OXIDES; POLYSTYRENES; PYROLYSIS; SELF ASSEMBLY; SOL-GELS; THIN FILMS; TRANSMISSION ELECTRON MICROSCOPY;

MESOSTRUCTURE; METHYL TRIETHOXYSILANE; SPHERICAL VOIDS; TILTING ANGLES;

SILICA;

EID: 0141682730     PISSN: 07437463     EISSN: None     Source Type: Journal    
DOI: 10.1021/la034310h     Document Type: Article

References (27)

1. Kresge, C.; Leonowicz, M.; Roth, W.; Vartuli, C.; Beck, J. Nature 1992, 359, 710.
2. (a) Huo, Q.; Margolese, D. I.; Clesla, U.; Feng, P.; Gler, T. E.; Sleger, P.; Leon, R.; Petroff, P. M.; Schuth, F.; Stucky, G. D. Nature 1994, 368, 317.
3. (b) Tanev, P. T.; Pinnavaia, T. J. Science 1995, 267, 865.
4. (c) Smarsly, B.; Goltner, C.; Antonietti, M.; Ruland, W.; Hoinkis, E. J. Phys. Chem. B 2001, 105, 831.
5. (a) Antonelli, D. M.; Ying, J. Y. Angew. Chem., Int. Ed. Engl. 1995, 34, 2014.
6. (b) Mann, S.; Ozin, G. A. Nature 1996, 382, 313.
7. (c) Ozin, G. A.; Chomski, E.; Khushalani, D.; Maclachlan, M. J. Curr. Opin. Colloid Interface Sci. 1998, 3, 181.
8. (a) Ogawa, M. J. Am. Chem. Soc. 1994, 116, 7941.
9. (b) Brinker, C. J.; Lu, Y.; Sellinger, A.; Fan, H. Adv. Mater. 1999, 11, 579.
10. Miller, R. D. Science 1999, 286, 421.
11. Yu, K.; Hurd, A. J.; Eisenberg, A. Brinker, C. J. Langmuir 2001, 17, 7961.
12. (a) Yu, K.; Smarsly, B.; Brinker, C. J. Mater. Res. Soc. Symp. Proc. 2002, 728, S1.9.
13. (b) Yu, K.; Smarsly, B.; Brinker, C. J. Adv. Funct. Mater. 2003, 13 (1), 47-52.
14. (c) Smarsly, B.; Xomeritakis, G.; Yu, K.; Liu, N.; Fan, H.; Assink, R. A.; Drewien, C. A.; Ruland, W.; Brinker, C. J. Langmuir 2003, 19, 7295-7301.
15. (d) Smarsly, B.; Yu, K.; Brinker, C. J. Stud. Surf. Sci. Catal. 2003, 146, 295-298.
16. Yu, K.; Drewien, C. A.; Hurd, A. J.; Brinker, C. J.; Eisenberg, A. Mater. Res. Soc. Symp. Proc. 2001, 672, O8.15.
17. (a) Price, C. In Developments in block copolymers; Goodman, I., Ed.; Applied Science Publishers: London, 1982; Vol. 1, p. 39
18. (b) Halperin, A.; Tirrel, M.; Lodge, T. P. Adv. Polym. Sci. 1992, 100, 31.
19. (c) Gao, Z.; Varshney, S. K.; Wong, S.; Eisenberg, A. Macromolecules 1994, 27, 7923.
20. (d) Yu, K.; Bartels, C.; Eisenberg, A. Langmuir 1999, 15, 7157.
21. (a) McConnell, G. A.; Gast, A. P.; Huang, J. S.; Smith, S. D. Phys. Rev. Lett. 1993, 71, 2102.
22. (b) Wanka, G.; Hoffmann, H.; Ulbricht, W. Macromolecules 1994, 27, 4145.
23. (a) Hoover, W. G.; Ree, F. H. J. Chem. Phys. 1968, 49, 3609.
24. (b) Scordari, F. Ionic Crystals. In Fundamentals of Crystallography; Giacovazzo, C., Ed.; Oxford University Press: Oxford, 1992; p 429.
25. (a) Matsen, M. W.; Bates, F. S.; Macromolecules 1996, 29, 1091.
26. (b) Bates, F. S.; Fredrickson, G. H. Annu. Rev. Chem. 1990, 41, 525.
27. Lu, M.; Brinker, C. J. Unpublished results. The onset of the silica condensation takes place in the very late stage of the EISA process.