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Volumn 42, Issue 20, 2003, Pages 6564-6574

Construction of multiporphyrin arrays using ruthenium and rhodium coordination to phosphines

Author keywords

[No Author keywords available]

Indexed keywords

COORDINATION COMPOUND; DIMER; LIGAND; NICKEL; PHOSPHINE DERIVATIVE; PORPHYRIN DERIVATIVE; RHODIUM COMPLEX; RUTHENIUM COMPLEX;

EID: 0141454932     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic034699w     Document Type: Article
Times cited : (44)

References (27)
  • 22
    • 0141622484 scopus 로고    scopus 로고
    • Private communication to the CCDC. CSD Refcode: HOJCOY
    • Darling, S. L.; Sanders, J. K. M.; Feeder, N. Private communication to the CCDC, 1999. CSD Refcode: HOJCOY.
    • (1999)
    • Darling, S.L.1    Sanders, J.K.M.2    Feeder, N.3
  • 23
    • 0141845826 scopus 로고    scopus 로고
    • note
    • -3 was observed at the center of the porphyrin cavity. This result was repeated for several different crystals and was interpreted therefore as a partial zinc atom, present in ca. 8% of the porphyrin molecules, probably as a result of incomplete demetalation during acidic workup in this particular sample. It should be noted that the structure of m-Fb-1 differs dramatically from that of m-Zn-1 (reported herein), and we conclude therefore that the gross structure is that of the free-base form. Literal interpretation of the X-ray results would suggest that the crystals analyzed actually comprise solid solutions of ca. 8% m-Zn-1 in a lattice of m-Fb-1.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.