Convenient one-pot synthesis of functional alkenyl pendant-containing silylene-divinylene polymers

Chemistry Letters

Volumn 32, Issue 7, 2003, Pages 580-581

  Rao, Tumula Venkateshwar ^a,b   Yamashita, Hiroshi ^a   Uchimaru, Yuko ^a   Asai, Michihiko ^a   Takeuchi, Kazuhiko ^a  

^a NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY AIST   (Japan)

^b CSIR INDIAN INSTITUTE OF PETROLEUM   (India)

Author keywords

[No Author keywords available]

Indexed keywords

ALKENYL GROUP; ALKYNE; BENZENE DERIVATIVE; CYCLOHEXYLAMINE; PALLADIUM; POLYMER;

ARTICLE; CHEMICAL REACTION; PHYSICAL CHEMISTRY; SYNTHESIS;

EID: 0141429067     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.580     Document Type: Article

References (8)

1. For recent progress: "Silicon-Containing Polymers," ed. by R. G. Jones, W. Ando, and J. Chojnowski, Kluwer, Dordrecht (2000).
2. H. Yamashita and Y. Uchimaru, Chem. Commun., 1999, 1763.
3. For some examples of polycarbosilanes and their applications: J. Ohshita, Yuki Gosei Kagaku Kyokaishi, 59, 11 (2001), see also: Ref. 4.
4. For recent studies on hydrosilylation polymerization: G. Kwak and T. Masuda, Kobunshi Ronbunshu, 59, 332 (2002), and references cited therein; A. Mori, E. Takahisa, H. Kajiro, Y. Nishihara, and T. Hiyama, Macromolecules, 33, 1115 (2000); D. S. Kim and S. C. Shim, J. Polym. Sci., Part A: Polym. Chem., 37, 2933 (1999).
5. For recent studies on hydrosilylation polymerization: G. Kwak and T. Masuda, Kobunshi Ronbunshu, 59, 332 (2002), and references cited therein; A. Mori, E. Takahisa, H. Kajiro, Y. Nishihara, and T. Hiyama, Macromolecules, 33, 1115 (2000); D. S. Kim and S. C. Shim, J. Polym. Sci., Part A: Polym. Chem., 37, 2933 (1999).
6. For recent studies on hydrosilylation polymerization: G. Kwak and T. Masuda, Kobunshi Ronbunshu, 59, 332 (2002), and references cited therein; A. Mori, E. Takahisa, H. Kajiro, Y. Nishihara, and T. Hiyama, Macromolecules, 33, 1115 (2000); D. S. Kim and S. C. Shim, J. Polym. Sci., Part A: Polym. Chem., 37, 2933 (1999).
7. n: C, 75.67; H, 5.44. Found: C, 75.38; H, 5.45.
8. 29Si NMR signals emerged at -20.9 and -18.8 ppm which corresponded to the (β,β)- and (β,α)-type isomers of 6, respectively.