Highly efficient palladium catalyst system for addition of trihydrosilanes to acetylenes and its application to thermally stable polycarbosilane synthesis

Chemical Communications

Volumn , Issue 17, 1999, Pages 1763-1764

  Yamashita, Hiroshi ^a   Uchimaru, Yuko ^a  

^a NATL INST OF MAT AND CHEM RES   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

ACETYLENE DERIVATIVE; BENZENE DERIVATIVE; PALLADIUM; SILANE DERIVATIVE;

ARTICLE; CATALYST; SYNTHESIS; THERMOSTABILITY;

EID: 0033533519     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/a905128g     Document Type: Article

References (11)

1. Comprehensive Handbook on Hydrosilylation, ed. B. Marciniec, Pergamon, Oxford, 1992; I. Ojima, Z. Li and J. Zhu, in The Chemistry of Organic Silicon Compounds, Vol. 2, ed. Z. Rappoport and Y. Apeloig, Wiley, Chichester, 1998, p. 1687.
2. Comprehensive Handbook on Hydrosilylation, ed. B. Marciniec, Pergamon, Oxford, 1992; I. Ojima, Z. Li and J. Zhu, in The Chemistry of Organic Silicon Compounds, Vol. 2, ed. Z. Rappoport and Y. Apeloig, Wiley, Chichester, 1998, p. 1687.
3. T.-Y. Luh and S.-T. Liu, in The Chemistry of Organic Silicon Compounds, Vol. 2, ed. Z. Rappoport and Y. Apeloig, Wiley, Chichester, 1998, p. 1793.
4. 3-catalysed addition of phenylsilane to RC≡CH (R = Ph, Hex) was reported, although byproduct (diphenylsilane) was also formed in the case of R = Hex. J. B. Baruah K. Osakada and T. Yamamoto, J. Mol. Catal. A: Chem., 1995, 101, 17.
5. Organolanthanide-catalysed hydrosilylation of internal acetylenes with phenylsilane has recently been reported. H. Schumann, M. R. Keitsch, J. Winterfeld, S. Mühle and G. A. Molander, J. Organomet. Chem., 1998, 559, 181 and references cited therein.
6. For recent intriguing examples of hydrosilylation polymerisation or cross-linking with monohydrosilyl groups, see (a) B. Boury, R. J. P. Corriu, D. Leclercq, P. H. Mutin, J.-M. Planeix and A. Vioux, Organometallics, 1991, 10, 1457;
7. (b) Y. Pang, S. Ijadi-Maghsoodi and T. J. Barton, Macromolecules, 1993, 26, 5671;
8. (c) G.-H. Wang, M.-W. Chen and W. P. Weber, Chem. Mater., 1993, 5, 1651;
9. (d) R.-M. Chen, Z. B. Deng, G. Sun, S.-T. Lee and T.-Y. Luh, Polym. Prepr., 1998, 39, 89;
10. (e) J. Hu and D. Y. Son, Macromolecules, 1998, 31, 4645 and references cited therein.
11. For photo- and/or electro-luminescence of arylene- and vinylene-containing silicon polymers, H. K. Kim, M.-K. Ryu and S.-M. Lee, Macromolecules, 1997, 30, 1236; ref. 5(d).