Cyclization of 5-hexenyl radicals from nitroxyl radical additions to 4-pentenylketenes and from the acyloin reaction

Canadian Journal of Chemistry

Volumn 81, Issue 6, 2003, Pages 697-704

  Henry Riyad, Huda ^a   Tidwell, Thomas T ^a  

^a UNIVERSITY OF TORONTO   (Canada)

Author keywords

Acyloin condensation; Free radical cyclization; Ketenes; TEMPO

Indexed keywords

ADDITION REACTIONS; CARBOXYLIC ACIDS; DERIVATIVES; NITROGEN COMPOUNDS; OLEFINS; SUBSTITUTION REACTIONS; THERMOANALYSIS;

CYCLIZATION REACTIONS;

PHOTOCHEMICAL REACTIONS;

2 BENZYLCYCLOPENTANOL; 4 PENTENYLKETENE; 5 HEXENYL RADICAL; CARBOXYLIC ACID DERIVATIVE; CYCLOPENTANE DERIVATIVE; CYCLOPROPYLCARBINYL RADICAL; HYDROCARBON; HYDROGEN; KETENE DERIVATIVE; NITROGEN; PIPERIDINE DERIVATIVE; RADICAL; SOLVENT; TETRAMETHYLPIPERIDINYLOXYL; TOLUENE; UNCLASSIFIED DRUG;

ACYLOIN CONDENSATION REACTION; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; CYCLIZATION; INFRARED SPECTROSCOPY; LYSIS; PHOTOCHEMISTRY; PROTON TRANSPORT; REACTION ANALYSIS; REACTION TIME; STRUCTURE ANALYSIS; WOLFF REARRANGEMENT;

EID: 0043234983     PISSN: 00084042     EISSN: None     Source Type: Journal    
DOI: 10.1139/v03-076     Document Type: Article

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