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Volumn 42, Issue 18, 2003, Pages 5560-5571

Difference in spin crossover pathways among saddle-shaped six-coordinated iron(III) porphyrin complexes

Author keywords

[No Author keywords available]

Indexed keywords

IRON COMPLEX; PORPHYRIN DERIVATIVE;

EID: 0042877156     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0300969     Document Type: Article
Times cited : (35)

References (70)
  • 2
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    • Scheidt, W. R.; Gouterman, M. In Iron Porphyrin, Part 1; Lever, A. B. P., Gray, H. B., Eds.; Addison-Wesley: Reading, MA, 1983; pp 89-139.
    • (1983) Iron Porphyrin, Part 1 , pp. 89-139
    • Scheidt, W.R.1    Gouterman, M.2
  • 3
    • 0002678025 scopus 로고    scopus 로고
    • Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: San Diego, CA, Chapter 16
    • Scheidt, W. R. In The Porphyrin Handbook; Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: San Diego, CA, 2000; Vol. 3, Chapter 16, pp 49-112.
    • (2000) The Porphyrin Handbook , vol.3 , pp. 49-112
    • Scheidt, W.R.1
  • 7
    • 0042404817 scopus 로고    scopus 로고
    • note
    • tBuNC, tert-butyl-isocyanide.
  • 14
    • 0003367774 scopus 로고    scopus 로고
    • Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: Burlington, MA
    • Weiss, R.; Gold, A.; Trautwein, A. X.; Terner, J. In The Porphyrin Handbook; Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: Burlington, MA, 2000; Vol. 3, pp 65-96.
    • (2000) The Porphyrin Handbook , vol.3 , pp. 65-96
    • Weiss, R.1    Gold, A.2    Trautwein, A.X.3    Terner, J.4
  • 20
    • 0002724520 scopus 로고    scopus 로고
    • Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: San Diego, CA, Chapter 36
    • Walker, F. A. In The Porphyrin Handbook; Kadish, K. M., Smith, K. M., Guilard, R., Eds.; Academic Press: San Diego, CA, 2000; Vol. 5, Chapter 36, pp 81-183.
    • (2000) The Porphyrin Handbook , vol.5 , pp. 81-183
    • Walker, F.A.1
  • 38
    • 0000020067 scopus 로고
    • Berliner, L. J., Reuben, J., Eds.; Plenum Press: New York
    • Walker, F. A.; Simonis, U. In NMR of Paramagnetic Molecules; Berliner, L. J., Reuben, J., Eds.; Plenum Press: New York, 1993; Vol. 12, pp 133-274.
    • (1993) NMR of Paramagnetic Molecules , vol.12 , pp. 133-274
    • Walker, F.A.1    Simonis, U.2
  • 39
    • 0003107740 scopus 로고
    • Lever, A. B. P., Gray, H. B., Eds.; Addison-Wesley: Reading, MA
    • Goff, H. M. In Iron Porphyrin, Part I; Lever, A. B. P., Gray, H. B., Eds.; Addison-Wesley: Reading, MA, 1983; pp 237-281.
    • (1983) Iron Porphyrin, Part I , pp. 237-281
    • Goff, H.M.1
  • 44
    • 0042905538 scopus 로고    scopus 로고
    • note
    • [Fe(OETPP)Cl] was reported to be an S = 5/2 spin state with approximately 40% S = 3/2 spin admixture.36 A later report has shown that the S = 3/2 contribution is much smaller, 4-10%.45
  • 52
    • 0002791918 scopus 로고
    • Lever, A. B. P., Gray, H. B., Eds.; Addison-Wesley: Reading, MA
    • Palmer, G. In Iron Porphyrin, Part II; Lever, A. B. P., Gray, H. B., Eds.; Addison-Wesley: Reading, MA, 1983; pp 43-88.
    • (1983) Iron Porphyrin, Part II , pp. 43-88
    • Palmer, G.1
  • 56
    • 0042905535 scopus 로고    scopus 로고
    • note
    • 1 electron configurations should be considered as isomers and exist as the different entities at 4.2 K;57 the former maintains the saddled structure while the latter has the saddled structure with ruffled contribution.58
  • 66
    • 0042905532 scopus 로고    scopus 로고
    • To be published
    • 4 previously reported;61 the average deviation of the β-pyrrole carbon atoms from the least-squares porphyrin plane is 1.04 Å in the former while it is 1.22 Å in the latter. The result is another piece of evidence supporting the rigid nature of the OETPP core as compared to the OMTPP core. Ohgo, Y.; Ikeue, T.; Takahashi, M.; Takeda, M.; Nakamura, M. To be published.
    • Ohgo, Y.1    Ikeue, T.2    Takahashi, M.3    Takeda, M.4    Nakamura, M.5


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.