Influence of nonplanarity and extended conjugation on porphyrin basicity

Inorganic Chemistry

Volumn 41, Issue 26, 2002, Pages 6944-6946

  Finikova, Olga S ^a   Cheprakov, Andrei V ^a   Carroll, Patrick J ^b   Dalosto, Sergio ^b   Vinogradov, Sergei A ^b  

^a MOSCOW STATE UNIVERSITY   (Russian Federation)

^b UNIVERSITY OF PENNSYLVANIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

BENZOPORPHYRIN DERIVATIVE; CYCLOHEXANE DERIVATIVE; MACROCYCLIC COMPOUND; PORPHYRIN DERIVATIVE;

ABSORPTION SPECTROSCOPY; ARTICLE; CHEMICAL REACTION; CHEMICAL STRUCTURE; PH; THERMODYNAMICS; X RAY CRYSTALLOGRAPHY;

CRYSTALLOGRAPHY, X-RAY; ELECTROCHEMISTRY; HYDROGEN-ION CONCENTRATION; MODELS, CHEMICAL; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; PORPHYRINS; THERMODYNAMICS;

EID: 0037203153     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0260522     Document Type: Article

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25. 3, 3607 reflections (24172 total) with F > 4σ(F), R1 = 0.0659, wR2 = 0.1503; Cambridge Crystallographic Data Centre depositions 188053 (3a) and 188054 (3d) contain the supplementary crystallographic data for this paper.
26. 3, 3607 reflections (24172 total) with F > 4σ(F), R1 = 0.0659, wR2 = 0.1503; Cambridge Crystallographic Data Centre depositions 188053 (3a) and 188054 (3d) contain the supplementary crystallographic data for this paper.
27. 4TCHPs from group A.
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30. oop, since in both cases the total distortion is dominated by the same mode, i.e., saddle distortion.