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Volumn 81, Issue 6, 2003, Pages 638-646
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Variation of the ease of α-sulfonyl carbanion formation with the orientation of different β-substituents: Experimental evidence for the generality of negative hyperconjugation as an important substituent effect
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Author keywords
Anomeric effect; Negative hyperconjugation; Stereoelectronic factors; Substituent effects; Sulfonyl carbanions
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Indexed keywords
IONS;
MOLECULAR STRUCTURE;
REACTION KINETICS;
STEREOCHEMISTRY;
SUBSTITUTION REACTIONS;
CONJUGATION REACTIONS;
SULFUR COMPOUNDS;
ALPHA SULFONYL CARBANION;
AMMONIUM DERIVATIVE;
ANION;
FUNCTIONAL GROUP;
UNCLASSIFIED DRUG;
ARTICLE;
CHEMICAL REACTION KINETICS;
CONJUGATION;
ELECTRON;
GEOMETRY;
STEREOCHEMISTRY;
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EID: 0042734608
PISSN: 00084042
EISSN: None
Source Type: Journal
DOI: 10.1139/v03-015 Document Type: Article |
Times cited : (4)
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References (29)
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