The β-effect of silicon in the orthogonal geometry

Journal of Organometallic Chemistry

Volumn 521, Issue 1-2, 1996, Pages 203-210

  Lambert, Joseph B ^a   Liu, Xiaoyang ^a  

^a NORTHWESTERN UNIVERSITY   (United States)

Author keywords

1 (Trimethylsilyl)cyclohexa 1,3 diene; Dihedral dependence; Hyperconjugation; Induction; Orthogonal geometry; Silicon; effect

Indexed keywords

EID: 0030598725     PISSN: 0022328X     EISSN: None     Source Type: Journal    
DOI: 10.1016/0022-328X(96)06228-6     Document Type: Article

References (19)

1. [1] D.D. Davis and H.M. Jacocks, J. Organomet. Chem., 206 (1981) 33.
2. [2] J.B. Lambert, R.W. Emblidge and S. Malany, J. Am. Chem. Soc., 115 (1993) 1417.
3. [3] S.G. Wierschke, J. Chandrasekhar and W.L. Jorgensen, J. Am. Chem. Soc., 107 (1985) 1496.
4. [4] M.R. Ibrahim and W.L. Jorgensen, J. Am. Chem. Soc., 111 (1989) 819.
5. [5] I. Fleming, Chem. Tracts, 6 (1993) 113.
6. [6] J.B. Lambert, Tetrahedron, 46 (1990) 2677.
7. [7] J.B. Lambert, G.-T. Wang, R.B. Finzel and D.H. Teramura, J. Am. Chem. Soc., 109 (1987) 7838.
8. [8] J.B. Lambert and E.C. Chelius, J. Am. Chem. Soc., 112 (1990) 8120.
9. [9] J.M. Renter, A. Sinha and R.G. Salomon, J. Org. Chem., 43 (1987) 2438.
10. [10] C. Shih and J.S. Swenton, J. Org. Chem., 47 (1982) 2825.
11. [11] R.M. Shapiro, J.H. Duncan, K. Tomer and W.G. Domben, J. Am. Chem. Soc., 90 (1968) 4762.
12. [12] R.V. Carr, R.V. Williams and L.A. Paquette, J. Org. Chem., 48 (1983) 4976.
13. [13] B.M. Trost, H.C. Arndt, P.E. Strege and T.R. Verhoeven, Tetrahedron Lett., (1976) 3857.
14. [14] H.C. Brown and P.J. Geoghegan, J. Org. Chem., 35 (1970) 1844.
15. [15] R.S. Tipson, J. Org. Chem., 9 (1994) 235.
16. [16] D.J. Raber, W.C. Neal, Jr., M.D. Dukes, J.M. Harris and D.L. Mount, J. Am. Chem. Soc., 100 (1978) 8137; J.M. Harris, D.L. Mount, M.R. Smith, W.C. Neal, Jr., M.D. Dukes and D.J. Raber, J. Am. Chem. Soc., 100 (1978) 8147.
17. [16] D.J. Raber, W.C. Neal, Jr., M.D. Dukes, J.M. Harris and D.L. Mount, J. Am. Chem. Soc., 100 (1978) 8137; J.M. Harris, D.L. Mount, M.R. Smith, W.C. Neal, Jr., M.D. Dukes and D.J. Raber, J. Am. Chem. Soc., 100 (1978) 8147.
18. [17] H. Lund and J. Bjerrum, Chem. Ber., 64 (1931) 210.
19. [18] E. Piers and I. Nagakur, Syn. Commun., 5 (1975) 193.