Resonance hyper-Raman scattering from conjugated organic donor-acceptor "push-pull" chromophores with large first hyperpolarizabilities

Journal of the American Chemical Society

Volumn 125, Issue 35, 2003, Pages 10520-10521

  Kelley, Anne Myers ^a,b   Leng, Weinan ^a   Blanchard Desce, Mireille ^a  

^a KANSAS STATE UNIVERSITY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACETONE; CYCLOHEXANE; ORGANIC COMPOUND;

ABSORPTION SPECTROSCOPY; ARTICLE; CHROMATOPHORE; DIPOLE; ELECTRON; PHOTON; POLARIZATION; RAMAN SPECTROMETRY; VIBRATION;

EID: 0042355714     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja036570r     Document Type: Article

References (29)

1. (a) Blanchard-Desce, M.; Alain, V.; Bedworth, P. V.; Marder, S. R.; Fort, A.; Runser, C.; Barzoukas, M.; Lebus, S.; Wortmann, R. Chem. Eur. J. 1997, 3, 1091-1104.
2. (b) Shi, Y.; Zhang, C.; Zhang, H.; Bechtel, J. H.; Dalton, L. R.; Robinson, B. H.; Steier, W. H. Science 2000, 288. 119-122.
3. (c) Alain, V.; Rédoglia, S.; Blanchard-Desce, M.; Lebus, S.; Lukaszuk, K.; Wortmann, R.; Gubler, U.; Bosshard, C.; Günter, P. Chem. Phys. 1999, 245, 51-71.
4. (d) Dalton, L.; Harper, A.; Ren, A.; Wang, F.; Todorova, G.; Chen, J.; Zhang, C.; Lee, M. Ind. Eng. Chem. Res. 1999, 38, 8-33.
5. (a) Oudar, J. L.; Chemla, D. S. J. Chem. Phys. 1977, 66, 2664-2668.
6. (b) Lu, D.; Chen, G.; Perry, J. W.; Goddard, W. A., III. J. Am. Chem. Soc. 1994, 116, 10679-10685.
7. (c) Thompson, W. H.; Blanchard-Desce, M.; Hynes, J. T. J. Phys. Chem. A 1998, 102, 7712-7722.
8. (d) Willetts, A.; Rice, J. E.; Burland, D. M.; Shelton, D. P. J. Chem. Phys. 1992, 97, 7590-7599.
9. (e) Barzoukas, M.; Runser, C.; Fort, A.; Blanchard-Desce, M. Chem. Phys. Lett. 1996, 257, 531-537.
10. (f) Risser, S. M.; Beratan, D. N.; Marder, S. R. J. Am. Chem. Soc. 1993, 115, 7719-7728.
11. (a) Hendrickx, E.; Clays, K.; Persoons, A. Acc. Chem. Res. 1998, 31, 675-683.
12. (b) Kaatz, P.; Shelton, D. P. J. Chem. Phys. 1996, 105, 3918-3929.
13. Kelley, A. M. J. Opt. Soc. Am. B. 2002, 19, 1890-1900.
14. Hsu, C.-C.; Liu, S.; Wang, C. C.; Wang, C. H. J. Chem. Phys. 2001, 114, 7103-7108.
15. (a) Kelley, A. M. J. Phys. Chem. A 1999, 103, 6891-6903.
16. (b) Moran, A. M.; Delbecque, C.; Kelley, A. M. J. Phys. Chem. A 2001, 105, 10208-10219.
17. (c) Moran, A. M.; Kelley, A. M. J. Chem. Phys. 2001, 115, 912-924.
18. (d) Moran, A. M.; Egolf, D. S.; Blanchard-Desce, M.; Kelley, A. M. J. Chem. Phys. 2002, 116, 2542-2555.
19. (e) Moran, A. M.; Bartholomew, G. P.; Bazan, G. C.; Kelley, A. M. J. Phys. Chem. A 2002, 106, 4928-4937.
20. (f) Moran, A. M.; Blanchard-Desce, M.; Kelley, A. M. Chem. Phys. Lett. 2002, 358, 320-327.
21. Stadler, S.; Bourhill, G.; Bräuchle, C. J. Phys. Chem. 1996, 100, 6927-6934.
22. -1. No intensity corrections have been applied to the displayed spectra. Resonance Raman spectra were obtained in an identical manner except that the YAG second harmonic (<0.1 mJ/pulse) was used for excitation and a 532 nm notch filter was placed before the spectrograph entrance slit to reduce stray light. Both HR and RR spectra were accumulated for 5-15 min. No power dependence of the spectral features was observed over a factor of about 10 for either RR or HR spectra. The synthesis and characterization of chromophores 1b-5, 2b-4, and 2b-5 is described in ref 9.
23. Alain, V.; Thouin, L.; Blanchard-Desce, M.; Gubler, U.; Bosshard, C.; Günter, P.; Muller, J.; Fort, A.; Barzoukas, M. Adv. Mater. 1999, 11, 1210-1214.
24. Le Duff, A.-C.; Canva, M.; Lévy, Y.; Brun, A.; Ricci, V.; Pliska, T.; Meier, J.; Stegeman, G. I.; Chaput. F.; Boilot, J.-P.; Toussaere, E. J. Opt. Soc. Am. B 2001, 18, 1827-1831.
25. Ziegler, L. D. J. Roman Spectrosc. 1990, 21, 769-779.
26. Mizuno, M.; Hamaguchi, H.; Tahara, T. J. Phys. Chem. A 2002, 106, 3599-3604.
27. Myers, A. B.; Mathies, R. A. In Biological Applications of Raman Spectroscopy: Spiro, T. G., Ed.; Wiley: New York, 1987; Vol. 2, pp 1-58.
28. This implies exponential dephasing, which is rarely valid for molecules in fluid solution. However, application of a more sophisticated model for solvent broadening should not affect our conclusions about relative RR and RHR intensity patterns.
29. Kauranen, M.; Persoons, A. J. Chem. Phys. 1996, 104, 3445-3456.