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The Bridgman technique has been applied in various ternary and quaternary bismuth chalcogenide compounds and large and highly oriented ingots with long parallel needles were grown. Kyratsi, Th.; Chung, D.-Y.; Choi, K.-S.; Dyck, J. S.; Chen, W.; Uher, C.; Kanatzidis, M. G. Mater. Res. Soc. Symp. Proc. 2000, 626, Z8.8.1.
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