High Thermopower and Low Thermal Conductivity in Semiconducting Ternary K-Bi-Se Compounds. Synthesis and Properties of β-K2Bi8Se13 and K2.5Bi8.5Se14 and Their Sb Analogues

Chemistry of Materials

Volumn 9, Issue 12, 1997, Pages 3060-3071

  Chung, Duck Young ^a   Choi, Kyoung Shin ^a   Iordanidis, Lykourgos ^a   Schindler, Jon L ^b   Brazis, Paul W ^b   Kannewurf, Carl R ^b   Chen, Baoxing ^c   Hu, Siqing ^c   Uher, Ctirad ^c   Kanatzidis, Mercouri G ^a  

^a MICHIGAN STATE UNIVERSITY   (United States)

^b Northwestern University   (United States)

^c UNIVERSITY OF MICHIGAN   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000196808     PISSN: 08974756     EISSN: None     Source Type: Journal    
DOI: 10.1021/cm970397e     Document Type: Article

References (51)

1. (a) Jeon, H.-H.; Ha, H.-P.; Hyun, D.-B.; Shim, J.-D. J. Phys. Chem. Solids 1991, 4, 579-585.
2. (b) Testardi, L. R.; Bierly, J. N. Jr.; Donahoe, F. J. J. Phys. Chem. Solids 1962, 23, 1209.
3. (c) Champness, C. H.; Chiang, P. T.; Parekh, P. Can. J. Phys. 1965, 43, 653-659;
4. (d) 1967, 45, 3611-3626.
5. (a) Yim, W. M.; Fitzke, E. V. J. Electrochem. Soc. 1968, 115, 556-560.
6. (b) Yim, W. M.; Fitzke, E. V.; Rosi, F. D. J. Mater. Sci. 1966, 1, 52-65.
7. (c) Borkowski, K.; Przyluski, J. Mater. Res. Bull. 1987, 22, 381-387.
8. (a) Chizhevskaya, S. N.; Shelimova, L. E. Inorg. Mater. 1995, 31, 1083-1095.
9. (b) Horák, J.; Cermák, K.; Koudelka, L. J. Phys. Chem. Solids 1986, 47, 805-809.
10. (c) Lostak, P.; Horák, J.; Koudelka, L. Phys. Status Solidi 1983, 76, k71-k75.
11. (d) Zalar, S. M. Adv. Energy Conv. 1962, 2, 105-112.
12. (a) Boon, J. W. Recl. Trav. Chim. Pays-Bas 1944, 63, 32.
13. (b) Glemser, O.; Filcek, M. Z. Anorg. Allg. Chem. 1955, 279, 321-323.
14. (c) Gattow, G.; Zemann, J. Z. Anorg. Allg. Chem. 1955, 279, 324-327.
15. (d) Voroshilov, Y. V.; Peresh, E. Y.; Golovei, M. I. Inorg. Mater. 1972, 8, 777-778.
16. Kanischeva, A. S.; Mikhailov, J. N.; Lasarev, V. B.; Trippel, A. F. Dokl. Akad. Nauk., SSSR (Kryst.) 1980, 252, 96-99.
17. Schmitz, D.; Bronger, W. Z. Naturforsch. 1974, 296, 438-439.
18. Cordier, G.; Schäfer, H.; Schwidetzky, C. Rev. Chim. Miner. 1985, 22, 676-683.
19. Aurivillus, B. Acta Chem. Scand. 1983, A37, 399-407.
20. Cordier, G.; Schäfer, H.; Schwidetzky, C. Rev. Chim. Miner. 1985, 22, 631-638.
21. Volk, K.; Cordier, G.; Cook, R.; Schäfer, H. Z. Naturforsch. 1980, 356, 136-140.
22. Eisenmann, B.; Zagler, R. Z. Naturforsch. 1989, 44b, 249-256.
23. Sheldrick, W. S.; Häusler, H. J. Z. Anorg. Allg. Chem. 1988, 557, 98-104.
24. Sheldrick, W. S.; Kaub, J. Z. Anorg. Allg. Chem. 1986, 536, 114-118.
25. Sheldrick, W. S.; Häusler, H.-J. Z. Anorg. Allg. Chem. 1988, 561, 149-156.
26. Cordier, G.; Schäfer, H. Rev. Chim. Miner. 1981, 18, 218-223.
27. Dorrscheidt, W.; Schäfer, H. Z. Naturforsch. 1981, 36B, 410-414.
28. Cordier, G.; Schwidetzky, C.; Schäfer, H. Rev. Chim. Miner. 1882, 19, 179-186.
29. McCarthy, T. J.; Ngeyi, S.-P.; Liao, J.-H.; DeGroot, D.; Hogan, T.; Kannewurf, C. R.; Kanatzidis, M. G. Chem. Mater. 1993, 5, 331-340.
30. McCarthy, T. J.; Tanzer, T. A; Kanatzidis, M. G. J. Am. Chem. Soc. 1995, 117, 1294-1301.
31. (a) Kanatzidis, M. G.; McCarthy, T. J.; Tanzer, T. A.; Chen, L.-H.; Iordanidis, L.; Hogan, T.; Kannewurf, C. R.; Uher, C.; Chen, B. Chem. Mater. 1996, 8, 1465-1474.
32. (b) Kanatzidis, M. G.; McCarthy, T. J.; Tanzer, T. A.; Chen, L.-H.; Hogan, T.; Kannewurf, C. R.; Iordanidis, L. Mater. Res. Soc. Symp. Proc. 1996, 410, 37-43.
33. (c) Chung, D.-Y.; Hogan, T.; Schindler, J.; Iordanidis, L.; Brazis, P.; Kannewurf, C. R.; Chen, B.; Uher, C.; Kanatzidis, M. G. Mat. Res. Soc. Symp. Proc. 1997, 478, 333-344.
34. (a) Chung, D.-Y.; Jobic, S.; Hogan, T.; Kannewurf, C. R.; Brec, R.; Rouxel, J.; Kanatzidis, M. G. J. Am. Chem. Soc., in press.
35. (b) Chung, D.-Y.; Jobic, S.; Hogan, T.; Kannewurf, C. R.; Brec, R.; Rouxel, J.; Kanatzidis, M. G. Mat. Res. Soc. Symp. Proc. 1997, 453, 15-22.
36. McCarthy, T. J.; Kanatzidis, M. G. Inorg. Chem. 1994, 33, 1205-1211.
37. Choi, K.-S.; Iordanidis, L.; Chondroudis, K.; Kanatzidis, M. G. Inorg. Chem. 1997, 36, 3804-3805.
38. (a) Gildart, L.; Kline, J. M.; Martox, D. M. J. Phys. Chem. Solids 1961, 28, 246.
39. (b) Nayak, B. B.; Acharya, H. N. J. Mater. Sci. 1986, 21, 46.
40. (a) Wendlandt, W. W.; Hecht, H. G. Reflectance Spectroscopy; Interscience Publishers: New York, 1966.
41. (b) Kotüm, G. Reflectance Spectroscopy; Springer-Verlag: New York, 1969.
42. (c) Tandon, S. P.; Gupta, J. P. Phys. Status Solidi 1970, 38, 363-367.
43. (a) Lyding, J. W.; Marcy, H. O.; Marks, T. J.; Kannewurf, C. R. IEEE Trans. Instrum. Meas. 1988, 37, 76-80.
44. (b) Chaikin, P. I.; Kawk, J. F. Rev. Sci. Instrum. 1975, 46, 218-220.
45. Chung, D.-Y.; Kanatzidis, M. G., work in progress.
46. Smith, R. A. Semiconductors, 2nd ed.; Cambridge University Press: New York, 1978.
47. 3 are 0.13 and 0.27 eV, respectively. CRC Handbook of Chemistry and Physics, 71th ed.; Lide, D. R., Ed.; CRC Press: Boca Raton, FL, 1990; pp 12-62.
48. Encyclopedia of Materials Science and Engineering; Thermoelectric Semiconductors; MIT Press: Cambridge, MA; Pergamon Press: Oxford, 1986; p 4968.
49. Slack, G. A. In CRC Handbook of Thermoelectrics; Rowe, D. M., Ed.; CRC Press: Boca Raton, FL, 1995; pp 407-440.
50. Kittel, C. Introduction to Solid State Physics, 6th ed.; John Wiley & Sons, Inc.: New York, 1986; p 150.
51. Scherrer, H.; Scherrer, S. CRC Handbook of Thermoelectrics; Rowe, D. M., Ed.; CRC Press: Boca Raton, FL, 1995; pp 211-237.