Total synthesis of dumsin. 1. Retrosynthetic strategy and the elaboration of key intermediates from (-)-bornyl acetate

Journal of Organic Chemistry

Volumn 68, Issue 18, 2003, Pages 6905-6918

  Paquette, Leo A ^a   Hong, Fang Tsao ^a  

^a OHIO STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

DEFERRED OXIDATION;

MOLECULAR STRUCTURE; OXIDATION; SYNTHESIS (CHEMICAL);

ORGANIC COMPOUNDS;

12BETA ACETOXYHARRISONIN; 3 O ACETYLHYDROXYCHINOLAL; 4 HYDROXYCINNAMOYLRUTAEVIN; ACETAL; ALDEHYDE; ANION; AZADIRACHTIN; BORNYL ACETATE; CYCLOPENTENE DERIVATIVE; DUMSIN; ELEGANTIN A; JANGOMOLIDE; LIMONIN; LIMONOID; MELIANOLIDE; NORBORNENE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; COPE REARRANGEMENT; DRUG SYNTHESIS; OXIDATION;

AFRICA, EASTERN; BORNANES; CRYSTALLOGRAPHY, X-RAY; INDICATORS AND REAGENTS; MAGNETIC RESONANCE SPECTROSCOPY; MODELS, MOLECULAR; MOLECULAR CONFORMATION; OXIDATION-REDUCTION; PLANTS, MEDICINAL; SPECTROMETRY, MASS, FAST ATOM BOMBARDMENT; SPECTROPHOTOMETRY, INFRARED; STEREOISOMERISM;

EID: 0041336838     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo0301346     Document Type: Article

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