Chemistry of insect antifeedants from Azadirachta indica (Part 22): Functionalisation of the decalin fragment of azadirachtin via a Claisen rearrangement reaction

Synlett

Volumn , Issue 8, 1999, Pages 1295-1297

  Ley, Steven V ^a   Gutteridge, Clare E ^a   Pape, Andrew R ^a   Spilling, Christopher D ^b   Zumbrunn, Cornelia ^a  

^a UNIVERSITY OF CAMBRIDGE   (United Kingdom)

^b UNIVERSITY OF MISSOURI ST LOUIS   (United States)

Author keywords

Antifeedant; Azadirachtin; Claisen rearrangement

Indexed keywords

AZADIRACHTA INDICA EXTRACT; AZADIRACHTIN; CYCLOPENTENE DERIVATIVE; DECALIN; FUNCTIONAL GROUP; INSECTICIDE;

ARTICLE; NUCLEAR OVERHAUSER EFFECT; REACTION ANALYSIS; STEREOCHEMISTRY; SYNTHESIS;

EID: 0032793157     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-1999-2802     Document Type: Article

References (15)

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9. Recent publications by Murai et al. have further motivated us to report our results in a related area: Ishihara, J.; Fukuzaki, T.; Murai, A.; Tetrahedron Lett. 1999, 40, 1907. Ishihara, J.; Yamamoto, Y.; Kanoh, N.; Murai, A.; Tetrahedron Lett. 1999, 40, 4387.
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12. +
13. +
14. The reaction is sensitive to traces of acid. The use of base-washed glassware is therefore essential.
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