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Volumn 121, Issue 40, 1999, Pages 9307-9312

Nonlinear effects in kinetic resolutions

Author keywords

[No Author keywords available]

Indexed keywords

EPOXIDE; LIGAND; SULFOXIDE;

EID: 0040292267     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja991921g     Document Type: Article
Times cited : (60)

References (52)
  • 3
    • 26444466057 scopus 로고
    • For early examples of asymmetric amplification, refer to: (a) Wynberg, H.; Feringa, B. Tetrahedron 1976, 32, 2831. (b) Agami, C.; Levisalles, J.; Puchot, C. J. Chem. Soc., Chem. Commun. 1985, 441.
    • (1976) Tetrahedron , vol.32 , pp. 2831
    • Wynberg, H.1    Feringa, B.2
  • 13
    • 0029559848 scopus 로고
    • The tremendous asymmetric amplifications observed in multistage reactions involving asymmetric autocatalysis should be especially noted: (a) Soai, K.; Shibata, T.; Morioka, H.; Choji, K. Nature 1995, 378, 767. (b) Shibata, T.; Yamamoto, J.; Matsumoto, N.; Yonekubo, S.; Osanai, S.; Soai, K. J. Am. Chem. Soc. 1998, 120, 12157. (c) Shibata, T.; Yonekubo, S.; Soai, K. Angew. Chem., Int. Ed. Engl. 1999, 38, 659.
    • (1995) Nature , vol.378 , pp. 767
    • Soai, K.1    Shibata, T.2    Morioka, H.3    Choji, K.4
  • 14
    • 0032567211 scopus 로고    scopus 로고
    • The tremendous asymmetric amplifications observed in multistage reactions involving asymmetric autocatalysis should be especially noted: (a) Soai, K.; Shibata, T.; Morioka, H.; Choji, K. Nature 1995, 378, 767. (b) Shibata, T.; Yamamoto, J.; Matsumoto, N.; Yonekubo, S.; Osanai, S.; Soai, K. J. Am. Chem. Soc. 1998, 120, 12157. (c) Shibata, T.; Yonekubo, S.; Soai, K. Angew. Chem., Int. Ed. Engl. 1999, 38, 659.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 12157
    • Shibata, T.1    Yamamoto, J.2    Matsumoto, N.3    Yonekubo, S.4    Osanai, S.5    Soai, K.6
  • 15
    • 0033105631 scopus 로고    scopus 로고
    • The tremendous asymmetric amplifications observed in multistage reactions involving asymmetric autocatalysis should be especially noted: (a) Soai, K.; Shibata, T.; Morioka, H.; Choji, K. Nature 1995, 378, 767. (b) Shibata, T.; Yamamoto, J.; Matsumoto, N.; Yonekubo, S.; Osanai, S.; Soai, K. J. Am. Chem. Soc. 1998, 120, 12157. (c) Shibata, T.; Yonekubo, S.; Soai, K. Angew. Chem., Int. Ed. Engl. 1999, 38, 659.
    • (1999) Angew. Chem., Int. Ed. Engl. , vol.38 , pp. 659
    • Shibata, T.1    Yonekubo, S.2    Soai, K.3
  • 36
    • 0031593113 scopus 로고    scopus 로고
    • Blackmond, D. G. J. Am. Chem. Soc. 1997, 119, 12934. Blackmond, D. G. J. Am. Chem. Soc. 1998, 120, 13349.
    • (1997) J. Am. Chem. Soc. , vol.119 , pp. 12934
    • Blackmond, D.G.1
  • 37
    • 0032583432 scopus 로고    scopus 로고
    • Blackmond, D. G. J. Am. Chem. Soc. 1997, 119, 12934. Blackmond, D. G. J. Am. Chem. Soc. 1998, 120, 13349.
    • (1998) J. Am. Chem. Soc. , vol.120 , pp. 13349
    • Blackmond, D.G.1
  • 44
    • 0345061023 scopus 로고    scopus 로고
    • note
    • This is calculated from eq 12, obtaining β from K by the equation of Kagan (see ref 24). The calculation of β is equally valid for asymmetric catalysis and kinetic resolutions.
  • 46
    • 0344198767 scopus 로고    scopus 로고
    • note
    • R versus ee of the binaphthol in ref 26 cannot be modeled without assuming a nonlinear effect. However, because all such plots are curved, their use to distinguish nonlinear effects is at best complicated.
  • 49
    • 0345492591 scopus 로고    scopus 로고
    • note
    • Unlike Figure 3, HKR reactions in THF appear to increase somewhat in selectivity as the reaction proceeds, with upward deviation of a graph of the enantiomeric excess obtained versus fractional conversion, compared to the theoretical curve. The DKEE thus changes somewhat as the reaction proceeds.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.