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note
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The exciton binding energies are dominated by the conduction band mass, and hence the energy differences in the three ground-state excitons are due to the splitting of the valence band by the hexagonal crystal-field and the spin-orbit interaction.
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note
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We follow the valence band ordering of Thomas and Hopfield (Refs. 6 and 7) in this work. There has been considerable controversy regarding the ordering. See the recent article by Reynolds et al. (Ref. 12). Rowe et al. have investigated the effects of static uniaxial compressive stress on the valence band characteristics of bulk ZnO and supported the Thomas-Hopfield interpretation (Ref. 9). From our study, the sign of the splitting (Ref. 6) could not be determined because we could not access the strain range in which the nonlinearity on the strain effect becomes unnegligible.
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